Flexible Thermoelectric ZnO-Organic Superlattices on Cotton Textile Substrates by ALD/MLD
Abstract
The research leading to these results has received funding from the European Research Council under the European Union's Seventh Framework Programme (FP/2007-2013) / ERC Grant Agreement n. 339478. Acronym LAYERENG-HYBMAT. | openaire: EC/FP7/339478/EU//LAYERENG-HYBMAT ; The thermoelectric properties of both pristine ZnO and ZnO-organic superlattice thin films deposited on a cotton textile are investigated. The thin films are fabricated by atomic layer deposition/molecular layer deposition, using hydroquinone as the organic precursor for the superlattices. The resulting thin-film coatings are crystalline, in particular when deposited on a textile substrate with a thin predeposited Al2O3 seed layer. The thermoelectric properties of the ZnO and ZnO-organic superlattice coatings are comparable to those for thin films deposited on conventional inorganic substrates; Al doping can be employed to further improve the thermoelectric properties. The ZnO-organic superlattice thin films moreover show enhanced resistance to mechanical strain. Due to the higher flexibility and lower thermal conductivity in comparison to pristine ZnO thin films, the ZnO-organic superlattice thin films are a possible material platform for flexible thermoelectrics that can be integrated in textiles and applied in wearable electronics. ; Peer reviewed
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