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peer-reviewed ; This topical review presents an overview of the formulation, characterisation and range of applications for polymer nanocomposites. After explaining how material properties at the nanometre scale can vary compared to those observed at longer length scales, typical methods used to formulate and characterise nanocomposites at laboratory and industrial scale will be described. The range of mechanical, electrical and thermal properties obtainable from nanocomposite materials, with examples of current commercial applications, will be outlined. Formulation and characterisation of nanoparticle, nanotube and graphene composites will be discussed by reference to nanoclay-based composites, as the latter are presently of most technological relevance. Three brief case studies are presented to demonstrate how structure/property relationships may be controlled in a variety of polymer nanocomposite systems to achieve required performance in a given application. The review will conclude by discussing potential obstacles to commercial uptake of polymer nanocomposites, such as inconsistent protocols to characterise nanocomposites, cost/performance balances, raw material availability, and emerging legislation, and will conclude by discussing the outlook for future development and commercial uptake of polymer nanocomposites.

Front Cover -- New Polymer Nanocomposites for Environmental Remediation -- Copyright -- Dedication -- Contents -- List of contributors -- Preface -- Polymer nanocomposites—An intro -- 1. Introduction -- 2. Polymer composites -- 3. Polymer nanocomposites (PNCs) -- 4. Conclusions -- 5. Websites of interest -- 6. List of famous research journals for PNCs -- References -- Chapter 1: Methods for preparation of nanocomposites in environmental remediation -- 1. Introduction -- 2. Nanomaterials and polymers used in polymer nanocomposites for environmental remediation -- 2.1. Nanomaterials -- 2.1.1. Iron (Fe) -- 2.1.2. Titanium dioxide (TiO2) -- 2.1.3. Cadmium sulfide (CdS) -- 2.1.4. Copper (Cu) -- 2.1.5. Iron/palladium (Fe/Pd) -- 2.2. Polymers -- 2.2.1. Poly(dimethylsiloxane) (PDMS) -- 2.2.2. Polyaniline (PANI) -- 2.2.3. Poly(hydroxybutyrate) (PHB) -- 2.2.4. Poly(vinyl pyrrolidone) (PVP) -- 2.2.5. Poly(methyl methacrylate) (PMMA) -- 2.2.6. Poly(vinylidene fluoride) (PVDF) -- 2.2.7. Polyethylene (PE) -- 2.2.8. Alginate -- 2.2.9. Carboxymethyl cellulose (CMC) -- 2.2.10. Chitosan -- 3. Methods for preparation of nanocomposites -- 3.1. Direct compounding -- 3.1.1. Solvent casting (exfoliation-adsorption) -- 3.1.2. Melt blending (melt intercalation) -- 3.1.3. Template synthesis (sol-gel technology) -- 3.1.4. Electrospinning -- 3.1.5. Self-assembly -- 3.2. In situ synthesis -- 4. New polymer nanocomposites for environmental remediation: Recent applications and studies -- 4.1. Metal/metal oxide polymer nanocomposites for environmental remediation -- 4.2. Magnetic polymer nanocomposites for environmental remediation -- 5. Conclusion -- References -- Chapter 2: Recent advances and perspectives in polymer-based nanomaterials for Cr(VI) removal -- 1. Introduction -- 2. Nanocomposites classifications -- 3. Polymer nanocomposites

Graphene has great potential as an ideal filler in nanocomposite polymeric materials for a wide range of applications such as coatings, adhesives, electronic devices, and electromagnetic shielding due to its unique mechanical, thermal and electrical properties. Fabrication of polymer/graphene nanocomposites with a high degree of dispersion of graphene in the polymer matrix remains a major challenge. Also, there is currently a significant thrust, driven by environmental and legislative factors, to replace solvent-borne formulations. This thesis presents a facile and industrially scalable method to synthesize waterborne colloidally stable polymer nanoparticles decorated with graphene oxide (GO) sheets via miniemulsion polymerization. Miniemulsion polymerization of styrene can be conducted successfully using GO as sole surfactant, but the polymerization rate is very low. However, introduction of SDS in the system results in a substantial rate enhancement as a result of alternative nucleation pathways in addition to monomer droplet nucleation in the form of nucleation of monomer droplets stabilized by both GO and SDS, nucleation involving free GO sheets as "seeds" as well as homogeneous nucleation. These results provide a mechanistic understanding of miniemulsion systems, which will aid in preparation of advanced nanocomposite materials based on polymer and graphene (oxide). Waterborne polymer/graphene coatings are of great interest due to their environmental benefits and electrical conductivity. Ambient temperature film-forming and electrically conductive polymer/reduced graphene oxide (rGO) nanocomposite films were prepared by environmentally friendly aqueous latex based routes, namely miniemulsion polymerization using graphene oxide (GO) as surfactant and "physical mixing" approaches (i.e. mixing of aqueous polymer latex with aqueous GO), followed by heat treatment of the films to convert GO to rGO. The distribution of GO sheets and the electrical conductivity depend strongly on the preparation method, with ...

International audience ; Poly(ethylene terephthalate) (PET) is one of the polymers most widely used in the packaging industry. However, it is highly desirable to enhance its barrier properties for applications, such as carbonated drinks and other rigid and flexible packaging applications. The nanocomposites route offers unique possibilities to enhance the properties of this material, provided that adequate thermally resistant and legislation complying nanoadditives are used. This study presents novel PET nanocomposites with enhanced barrier properties to oxygen, water, and limonene based on a new specifically developed food-contact-complying highly swollen montmorillonite grade, and, furthermore, presents and discusses morphological data. Moreover, given the current interest in the packaging industry to replace this material by other biopolyesters, a comparative barrier performance of PET nanocomposites versus that of biopolymers, such as poly(lactic acid) (PLA), polyhydroxyalkanoates (PHB, PHBV), and polycaprolactones (PCL) and their corresponding nanocomposites is also reported.

The insufficient access to drinking water is one of the most prevailing problems throughout the world. It is highly essential for future demands to bring wastewater to reusable form. Hence, water purification has been the focus and attention of many scientists and governmental agencies. The combination of adsorption and nanotechnology-oriented approach with conventional treatment methods has offered interesting benefits to treat waste water. During the last decade, hydrogels have been used as potential adsorbents for the removal of different types of water pollutants. The combination of hydrogels and nanomaterials with multifunctional framework leads to the development of hybrid hydrogels that gives synergistic effect to the novel materials. Because of their biocompatibility and ability to mix with other materials, hydrogels coupled with versatile chemical groups with well-defined three-dimensional porous structure were potentially used for removal of toxic pollutants in water. This article briefly reviews the recent progress in nanobased hydrogels with particular emphasis on wastewater treatment applications. © 2022 Author(s).

Structural and Dynamical Properties of Atactic Polystyrene in the Interface and Interphase Region Surrounding Grafted and Ungrafted Silica Nanoparticles The composite industry has long achieved enhanced material properties by mixing micro sized inorganic filler particles with a polymer matrix1,2. This is because the combination of two or more different materials can have a synergistic effect on the overall composite material properties imparting advantages that are absent in the individual constituents. A well-known example is that of adding carbon black as reinforcing material to increase tire strength, toughness, and resistance to tear and abrasion3,4. To achieve improved materials performance, the design of conventional composites has typically focused on reducing the dimensions of the filler particles. This is done in order to increase the filler surface area to enable greater interaction with the polymer matrix. Consequently, these efforts have received a significant boost with the dawn of the 'nano era'. Wherein experimental methods and tools are now used to synthesize, characterize, and investigate matter at the nano-scale level [10-9 m] which is close to molecular and atomic dimensions. The advent of such methods is exciting as it suddenly offers new possibilities of creating novel materials that can be tailored at very small dimensions. This expectation has been derived from the notion that the behavior of materials at their nanoscale level directly influences their microscopic properties and consequently their bulk macroscopic characteristics. As is typical in any emerging field, the challenge is to understand the fundamental aspects that control the final observable properties of these composite materials. In contrast to the behavior of materials in conventional composites, recent experimental observations of polymer nanocomposites have demonstrated multifunctional changes in their properties. Examples include - but are not limited to - the decrease in the polymer viscosity5, shifts in the polymer glass transition temperature6,7, and changes in the composite material's thermo-mechanical8,9 properties. However, what is still lacking and remains unclear are the fundamental explanations for the differences in the behavior between conventional composites and nanocomposites. In order to address questions pertaining to these differences, this PhD work was part of a large European Union consortium of universities and industrial partners, NanoModel. The aim of the group was to develop a unified scientific understanding from both experimentalists and theoreticians on the behavior of polymers in the presence of a surface. Such understanding of the important controlling parameters would ultimately support the design of industrial polymer nanocomposite materials. Therefore, both the structural and dynamical investigations always sought to address some of several important open questions that necessitated this work. These questions include among other things: (1) Does a nanoparticle influence the behavior of the surrounding polymer? (2) Since the dispersion state of the nanoparticles is known to control the resulting nanocomposite properties, which controlling parameters are important in obtaining a well-mixed polymer nanocomposite? (3) What role does the size/dimension of the nanoparticle play? (4) Is it necessary to graft or attach polymers to the filler particles, in other words, functionalizing the nanoparticles to facilitate their dispersion in the polymer melt? (5) How long should the grafted polymer chains be relative to the bulk polymer and which grafting density is optimal to achieve a good dispersion state? (6) To what extent are the polymer properties in the interface (next to the surface) and interphase (where grafted and bulk free polymer chains mix) region changed if they are at all? (7) Which parameters influence the width or extent of both the interface and interphase region? (8) Can we observe the same phenomena or changes by employing both experimental and theoretical approaches? Therefore, the contribution of this PhD thesis within the NanoModel framework was to investigate the structural and dynamical properties of atactic polystyrene in the vicinity of a silica nanoparticle as a model system for polymer nanocomposites at the atomistic level (see Figure 1.1 for a simulation snapshot). This model system was chosen because of its importance to the NanoModel partners since bulk polystyrene is an important, largely used, and well characterized polymer while silica is a typical traditional filler particle. Naturally, consortium partners like BASF would find it invaluable to produce new tailored plastics with superior properties to the traditional ones. At the same time, partners like BOSCH and CRP-FIAT would benefit from knowing the nanoparticle effect on the mechanical properties and the processing of the nanocomposite which directly impacts their injection molding processes for example. On the experimental front, Fribourg University, Juelich, and Epidoris were involved in nanocomposite sample preparation and characterization. These experimental results validated those obtained from computational studies from TU Darmstadt, National University of Athens, Trieste University, and BASF. Therefore, the influence of the nanoparticles of various diameters (3.0, 4.0, and 5.0 nm) and grafting states (0.0, 0.5, and 1.0 chains/nm2) on atactic polystyrene was studied. To perform this work, a computer molecular dynamics (MD) simulation tool, YASP10, was employed. This tool numerically solves Newton's equations of motion for a system of interacting atoms to generate a trajectory of their movements. Following this, the resulting trajectories can be analyzed for different properties that characterize the structure, dynamics, and thermodynamics of the system. The use of atomistic MD simulations has the advantage of being able to investigate both static and dynamic properties of a system in fine detail. The ensuing results have the benefit of being related to experimental observations such as those probed by nuclear magnetic resonance11 (NMR) and dielectric spectroscopy12 (DS) studies. Additionally, other experimental techniques like neutron, x-ray, and light scattering now allow the determination of the atomistic structure of a material. Thus, computer modeling techniques interface with and complement experimental methods in understanding the link between structural and dynamical properties of polymers. While many experimental5,6,9,13-20 investigations have been performed to study the behavior of polymers at surfaces, very few atomistic21-25 computer modeling studies have been done. This necessitates the development a unified theoretical and experimental understanding of the polymer static and dynamic modifications in the presence of a surface. This is important because such changes determine in part the overall material properties. Examples of these material properties include their mechanical strength, appearance, how well they can be processed, and the duration of the polymer aging process. Additionally, this work sets a foundation for coarse-grained simulations, which investigate longer polymer chains and bigger systems. Static and dynamic properties of polymers determine whether nanoparticles form clusters or are well dispersed in a polymer melt. This is a pivotal challenge in experimental techniques because it is difficult to control the dispersion of nanoparticles, which finally determines the resulting material properties. Parameters that influence the static, dynamic, and nanoparticle dispersion state include - but are not limited to - the nanoparticle size, grafting density, the ratio of the length of grafted to free chains, and surface-polymer interactions. Therefore, developing an understanding of how these parameters interplay with each other will aid in the control and tailoring of the final nanoparticle dispersion state. The first half of this cumulative PhD thesis, chapter 2, presents results of the atactic polystyrene structure around the nanoparticle. The quantities of interest were the polymer density, radius of gyration, and its orientation relative to the nanoparticle surface. The analysis of the computer simulation output trajectory files resolved these polymer properties as a function of distance from the nanoparticle surface to quantify the surface effect. Varying both the polymer grafting density and the nanoparticle surface curvature enabled the understanding of how these two parameters interplay and influence the polymer's structural properties. For instance, the extents of the polymer density modifications under the influence of the nanoparticle surface indicate the wettability of the surface by the polymer. This is important in mitigating adhesive failure and mechanical stress distribution in the nanocomposite material. At the same time, the density changes directly influence the polymer dynamical properties like the glass transition temperature and polymer aging processes. Therefore, understanding and being able to control these changes is vital since polymer properties like the elastic modulus and conductivity amongst many other physical properties change significantly around the polymer glass transition. These observations underscore not only the importance of the polymer in the interface region but also the width of the interphase region. The latter is influenced by the nanoparticle grafting state and the nanoparticle curvature as investigated in this work but also on the length ratio between the grafted and free polymer chains. While changes in the polymer radius of gyration give a measure of how stretched a polymer coil is, this has the effect of directly influencing the packing of polymer chains and their orientation. Additionally, the induced orientation of the polymer and its segments is important in processes that depend on transport properties such as electrical and thermal conductivity. Therefore, the different polymer structural properties are interlinked and understanding their cause-and-effect gives tuning parameters in the design of polymer nanocomposites. Complementary to structural properties discussed in chapter 2, chapter 3 forms the second half of this thesis and discusses the dynamical properties of the polymer. These included the mean-squared displacement (MSD) of the polymer chain center-of-mass and reorientational dynamics of intramolecular segment vectors. These quantities were also calculated under different nanoparticle grafting states and surface curvature. Changes in the polymer chain MSD and the reorientation of its end-to-end vector have given a measure of the global polymer mobility. To understand the local dynamics at the monomer level, the reorientation of a three-monomer and the C-Cpara segment vector as well as the backbone C-H bond vector was investigated (see Figure 1.2). The advantage of obtaining such a local resolution is that it allows for comparison with experimental NMR and DS studies which probe the C-H bond vector and the C-Cpara segment vectors, respectively. To develop a unified understanding, explanations of the dynamical property changes were linked to the previously observed structural properties either in the interface or interphase region, see chapter 2. The objectives to this thesis were to use the molecular dynamics simulation tool (YASP), setup the model system under investigation, perform the simulations, and write analysis programs to determine the different polymer properties. Therefore, I interpreted, understood, and explained my results in light of their interconnectedness as well as results from other simulations and experimental work on polymer nanocomposite systems. Finally, this work ends with chapter four which encompasses the conclusions and an outlook for further investigations.

The authors are grateful to Dr. Andris Fedotovs for photography of the samples. This research is funded by the Latvian Council of Science, project "Novel transparent nanocomposite oxyfluoride materials for optical applications", project No. LZP-2018/1-0335. ; Assessment of activator distribution in lanthanide doped nanocomposites is an important and challenging task. Oxyfluoride glass ceramics have been chosen as a model system to characterize incorporation efficiency of Eu3+ ions in CaF2 nanocrystals using a combination of X-ray diffraction (XRD) and electron paramagnetic resonance (EPR) techniques. Lattice constant changes induced by size mismatch of Eu3+ and Ca2+ ions have been used to evaluate Eu3+ content in CaF2. The distortion of CaF2 lattice due to incorporation of europium ions can be detected from EPR investigations via Gd3+ paramagnetic probe spectra. It is shown that ratio of different symmetry CaF2:Gd3+ centres and linewidth of EPR transitions can be used to monitor europium content in the crystalline phase of glass ceramics. --- / / / --- This is the preprint version of the following article: A. Antuzevics, G. Krieke, E. Pavlovska, U. Rogulis, Eu3+ ion distribution in oxyfluoride glass nanocomposites, Journal of Non-Crystalline Solids, 522, 119548 (2019), DOI https://doi.org/10.1016/j.jnoncrysol.2019.119548, which has been published in final form at https://www.sciencedirect.com/science/article/abs/pii/S0022309319304193. This article may be used for non-commercial purposes in accordance with Elsevier Terms and Conditions for Sharing and Self-Archiving. This work is licensed under a CC BY-NC-ND 4.0 license. ; Latvian Council of Science LZP-2018/1-0335; Institute of Solid State Physics, University of Latvia as the Center of Excellence has received funding from the European Union's Horizon 2020 Framework Programme H2020-WIDESPREAD-01-2016-2017-TeamingPhase2 under grant agreement No. 739508, project CAMART².