Suchergebnisse

The results of an experiment on studying the features of the crystal structure and magnetic studies of substitutional solid solutions of the Ni1–xCrxMnSb system (0 m х m 0.2) are presented. It was found that an increase in the concentration of chromium in solid solutions does not lead to significant changes in the size of the unit crystal cell. It was found that solid-phase quenching can be used to expand the limit of chromium solubility in Ni1–xCrxMnSb solid solutions. The temperature and field dependences of the specific magnetization of the synthesized compositions have been studied. It was found that the substitution of chromium for nickel in the NiMnSb compound leads to a decrease in the temperature of the "magnetic order – magnetic disorder" phase transformation with an increase in the concentration x from 0 to 20 mol.%. The values of specific magnetization and Curie temperature of hardened hard rasters are higher than those of slowly cooled ones. The results obtained contribute to the creation of a physical basis for the elemental base of spintronics.

Single-phase compositions in the MnSe–TmSe quasi-binary section have been synthesized by the method of reactions in the solid phase. The crystal structure of polycrystalline powders has been studied in CuKα-radiation. It was found that the samples in the concentration range 0  x  0.7 have a cubic structure of the space group Fm m3 . An increase in the concentration of Tm cations in the Mn1–xTmxSe compositions leads to an increase in the unit cell parameter a from 0.547 nm for the Mn0.975Tm0.025Se compound to 0.566 nm for the Mn0.3Tm0.7Se composition. Thin layers of Mn1–xTmxSe solid solutions were synthesized by the flash method on optically transparent glass substrates. The film thicknesses are in the range of values from 0.8 to 3.2 µm. It has been established that Mn1–xTmxSe films also have the system NaCl, S.G.: Fm m3 . The composition of the Mn1–xTmxSe films corresponds to the chemical composition of the MnSe–TmSe charge powders. In the temperature range ~ 80–900 K, the va lues of the specific magnetization and magnetic susceptibility of the studied selenides were measured. The results obtained make it possible to determine the temperature regimes for the synthesis of new magnetic semiconductor substances, including those in the film state. The synthesized substances can be used in multifunctional microelectronic devices, as well as in the development of new materials capable of operating in wide temperature ranges and under the influence of external magnetic fields.

The influence of synthesis conditions on the magnetic characteristics of composite materials based on iron powders ASC 100.29 (Sweden) and LiaoNing (China) is investigated. The surface of metallic iron powders is encapsulated by an insulating ferrite coating, consisting of iron oxides and phosphides. The synthesis was carried out at a temperature of 150 °C from a gaseous medium in a special reactor at a pressure of 1 atm. Insulating oxide coatings were applied both to the initial iron powder without treatment, and to previously annealed powders in an inert atmosphere and in a mixture of hydrogen-argon. To conduct studies of magnetic characteristics, cores in the form of rings were made by pressing method. The dependence of induction vs. magnitude of the magnetic field, magnetization reversal losses (hysteresis losses) in the full and in the private loop were recorded by an express magnetometer. The value of losses was calculated by the hysteresis loops area. The results show that composite low-frequency magnetic materials based on metallic iron ASC 100.29 and LiaoNing powders have similar values of magnetic parameters – almost identical B = f(H) dependencies, but the magnetization reversal losses for ASC 100.29 are significantly lower than for LiaoNing powder under equal insulating coatings synthesis conditions. It is possible to use such materials as magnetic cores in various electrical devices, such as cores of high-frequency transformers and a number of electrical machines. Since such materials can operate at frequencies from 1 kHz and higher, this will significantly reduce the overall dimensions and increase the efficiency of electrical products.

The results of an experiment on the study of the crystal and magnetic structures of substitutional solid solutions of the Ni0.90M0.10MnSb (M = Ti, V, Cr) systems using thermal neutron diffraction in the temperature range ~ 3–300 K are presented. It is found that all the studied compositions have ferromagnetic ordering along the c axis. In the spectra of Ni0.90V0.10MnSb and Ni0.90Cr0.10MnSb solid solutions, a reflection appears in the region 2Θ = 28.6°, which indicates the formation of antiferromagnetic ordering. It has been found that this reflection disappears at a temperature T = 75 K in Ni0.90V0.10MnSb, while it is observed in the spectrum of Ni0.90Cr0.10MnSb over the entire temperature range under study. Within the framework of density functional theory (DFT), an ab initio calculation of the crystal structure and magnetic moments for Ni1–xMxMnSb (M = Ti, V, Cr; x = 0; 0.125; 0.250) was carried out. It has been established that titanium, vanadium, and chromium ions participate in electron transfer only with Mn and Sb ions. The DFT results predict the existence of magnetic moments for Ti, V, and Cr ions. It was found that the spins of Ti, V, and Cr ions are antiferromagnetically coupled with the spins of Mn and Ni ions. The results obtained are of interest for the development of new concepts and models of structural design, which makes it possible to synthesize fundamentally new functional materials with already specified physical properties.