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Thermoelectric Properties of Solution-Processed n-Doped Ladder-Type Conducting Polymers
Ladder-type "torsion-free" conducting polymers (e.g., polybenzimidazobenzophenanthroline (BBL)) can outperform "structurally distorted" donor–acceptor polymers (e.g., P(NDI2OD-T2)), in terms of conductivity and thermoelectric power factor. The polaron delocalization length is larger in BBL than in P(NDI2OD-T2), resulting in a higher measured polaron mobility. Structure–function relationships are drawn, setting material-design guidelines for the next generation of conducting thermoelectric polymers. ; Funded by: Knut and Alice Wallenberg Foundation Swedish Foundation for Strategic Research Swedish Governmental Agency for Innovation Systems - VINNOVA. Grant Number: 2015-04859 Advanced Functional Materials Center at Linköping University. Grant Number: 2009-00971 Alexander von Humboldt Foundation
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