Suchergebnisse

It is well known that in the high-temperature superconductor YBa2Cu3O7−x (YBCO), oxygen vacancies (VO) control the carrier concentration, its critical current density and transition temperature. In this work, it is revealed that VO also allows the accommodation of local strain fields caused by large-scale defects within the crystal. We show that the nanoscale strain associated with Y2Ba4Cu8O16 (Y124) intergrowths— that are common defects in YBCO—strongly affect the venue and concentration of VO. Local probe measurements in conjunction with density-functional-theory calculations indicate a strain-driven reordering of VO from the commonly observed CuO chains towards the bridging apical sites located in the BaO plane and bind directly to the superconducting CuO2 planes. Our findings have strong implications on the physical properties of the YBCO, as the presence of apical VO alters the transfer of carriers to the CuO2 planes, confirmed by changes in the Cu and O core-loss edge probed using electron energy loss spectroscopy, and creates structural changes that affect the Cu–O bonds in the superconducting planes. In addition, the revelation of apical VO also has implications on modulating critical current densities and enhancing vortex pinning. ; We acknowledge financial support from the Spanish Ministry of Economy and Competitiveness through the 'Severo Ochoa' Programme for Centres of Excellence in R&D (SEV-2015-0496), and the COACHSUPENERGY project (SUMATE – RTI2018-095853-B-C21, co-financed by the European Regional Development Fund). B. M, R. G., J. G., T. P. and X. O also thank the European Union for its support under the EUROTAPES project (FP7-NMP-Large-2011-280432), ULTRASUPERTAPE project (ERC-2014-ADG-669504), and COST Action NANOCOHYBRI (CA16218), and from the Catalan Government under 2017-SGR-1519 and Xarmae. J. G. also acknowledges the Ramon y Cajal Program (RYC-2012-11709). S. H. and R. M. acknowledge financial support from the National Science Foundation (NSF) grant DMR-1806147. STEM imaging and analysis at 200 kV was sponsored by the U.S. Department of Energy, Office of Science, Basic Energy Sciences, Materials Sciences and Engineering Division, and STEM imaging at 100 kV was conducted at the Center for Nanophase Materials Sciences, which is a DOE Office of Science User Facility. Computations in this work benefited from the use of the Extreme Science and Engineering Discovery Environment (XSEDE), which is supported by NSF grants ACI-1053575 and ACI-1548562. ; Peer reviewed