Suchergebnisse

Nanoscale devices in which the interaction with light can be configured using external control signals hold great interest for next-generation optoelectronic circuits. Materials exhibiting a structural or electronic phase transition offer a large modulation contrast with multi-level optical switching and memory functionalities. In addition, plasmonic nanoantennas can provide an efficient enhancement mechanism for both the optically induced excitation and the readout of materials strategically positioned in their local environment. Here, we demonstrate picosecond all-optical switching of the local phase transition in plasmonic antenna-vanadium dioxide (VO2) hybrids, exploiting strong resonant field enhancement and selective optical pumping in plasmonic hotspots. Polarization- and wavelength-dependent pump–probe spectroscopy of multifrequency crossed antenna arrays shows that nanoscale optical switching in plasmonic hotspots does not affect neighboring antennas placed within 100 nm of the excited antennas. The antenna-assisted pumping mechanism is confirmed by numerical model calculations of the resonant, antenna-mediated local heating on a picosecond time scale. The hybrid, nanoscale excitation mechanism results in 20 times reduced switching energies and 5 times faster recovery times than a VO2 film without antennas, enabling fully reversible switching at over two million cycles per second and at local switching energies in the picojoule range. The hybrid solution of antennas and VO2 provides a conceptual framework to merge the field localization and phase-transition response, enabling precise, nanoscale optical memory functionalities. ; This work was financially supported by EPSRC through research grant EP/J011797/1. OLM acknowledges support through an EPSRC Early Career Fellowship EP/J016918/1. LB, NZ and JA acknowledge financial support from Project No. FIS2013-41184-P of the Spanish Ministry of Economy and Competitiveness, project ETORTEK IE14-393 NANOGUNE'14 of the Department of Industry of the Government of the Basque Country, and support from the Basque Department of Education and the UPV-EHU (Grant No. IT-756-13). ; Peer reviewed

Resumen del trabajo presentado a la Conferencia Española de Nanofotónica (CEN), celebrada en Vigo del 20 al 22 de septiembre de 2021. ; LB, NZ and JA acknowledge MINECO (FIS2016-80174-P), the Department of Education of the Basque Government (IT1164-19) and the Department of Industry of the Basque Government (Elkartek KK-2018/0000). OM and BC acknowledge EPSRC (EP/J016918/1 and EP/M009122/1). ; Peer reviewed

The ultrafast concentration of electromagnetic energy in nanoscale volumes is one of the key features of optical nanoantennas illuminated at their surface plasmon resonances. Here, we drive the insulator to metal phase transition in vanadium dioxide (VO2) using a laser-induced pumping effect obtained by positioning a single gold nanoantenna in proximity to a VO2 thermochromic material. We explore how the geometry of the single nanoantenna affects the size and permittivity of the nanometer-scale VO2 regions featuring phase transition under different pumping conditions. The results reveal that a higher VO2 phase transition effect is obtained for pumping of the longitudinal or transversal localized surface plasmon depending on the antenna length. This characterization is of paramount importance since the single nanoantennas are the building blocks of many plasmonic nanosystems. Finally, we demonstrate the picosecond dynamics of the VO2 phase transition characterizing this system, useful for the realization of fast nano-switches. Our work shows that it is possible to miniaturize the hybrid plasmonic-VO2 system down to the single-antenna level, still maintaining a controllable behavior, fast picosecond dynamics, and the features characterizing its optical and thermal response. ; LB, NZ, and JA acknowledge financial support from Spanish MICIN (DOI 10.13039/501100004837) through Project Ref. No. PID2019-107432GB-I00, from the Department of Education of the Basque Government under project IT1164-19 and the Department of Industry of the Basque Government under Elkartek project KK-2018/0000. OM and BC acknowledge support from EPSRC (DOI 10.13039/501100000266) through grants EP/J016918/1 and EP/M009122/1. ; Peer reviewed