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51 pags., 35 figs., 1 tab., 5 apps. ; The atmospheres of synchronously rotating exoplanets are intrinsically 3D, and fast vertical and horizontal winds are expected to mix the atmosphere, driving the chemical composition out of equilibrium. Due to the longer computation times associated with multidimensional forward models, horizontal mixing has only been investigated for a few case studies. In this paper, we aim to generalize the impact of horizontal and vertical mixing on the chemistry of exoplanet atmospheres over a large parameter space. We do this by applying a sequence of post-processed forward models for a large grid of synchronously rotating gaseous exoplanets, where we vary the effective temperature (between 400 and 2600 K), surface gravity, and rotation rate. We find that there is a dichotomy in the horizontal homogeneity of the chemical abundances. Planets with effective temperatures below 1400 K tend to have horizontally homogeneous, vertically quenched chemical compositions, while planets hotter than 1400 K exhibit large compositional day-night differences for molecules such as CH4. Furthermore, we find that the planet's rotation rate impacts the planetary climate, and thus also the molecular abundances and transmission spectrum. By employing a hierarchical modelling approach, we assess the relative importance of disequilibrium chemistry on the exoplanet transmission spectrum, and conclude that the temperature has the most profound impact. Temperature differences are also the main cause of limb asymmetries, which we estimate could be observable with the James Webb Space Telescope. This work highlights the value of applying a consistent modelling setup to a broad parameter space in exploratory theoretical research. ; RB is a PhD fellow of the Research Foundation – Flanders (FWO). LD acknowledges support from the FWO research grant G086217N. LC acknowledges support by the DFG grant CA 1795/3. OV thanks the CNRS/INSU Programme National de Planetologie ´ (PNP) and CNES for funding support. MA acknowledges support from Spanish MICIU through grants RyC-2014-16277, AYA2016- 75066-C2-1-P, PID2019-106110GB-I00, and PID2019-107115GBC21. PM acknowledges support from the European Research Council under the European Union's Horizon 2020 research and innovation program under grant agreement no. 832428. The computational resources and services used in this work were provided by the VSC (Flemish Supercomputer Center), funded by the Research Foundation Flanders (FWO) and the Flemish Government – department EWI.

Context. Theoretical studies predict the presence of thermal inversions in the atmosphere of highly irradiated gas giant planets. Recent observations have identified these inversion layers. However, the role of different chemical species in their formation remains unclear. Aims. We search for the signature of the thermal inversion agents TiO and Fe in the dayside emission spectrum of the ultra-hot Jupiter WASP-33b. Methods. The spectra were obtained with CARMENES and HARPS-N, covering different wavelength ranges. Telluric and stellar absorption lines were removed with SYSREM. We cross-correlated the residual spectra with model spectra to retrieve the signals from the planetary atmosphere. Results. We find evidence for TiO at a significance of 4.9σ with CARMENES. The strength of the TiO signal drops close to the secondary eclipse. No TiO signal is found with HARPS-N. An injection-recovery test suggests that the TiO signal is below the detection level at the wavelengths covered by HARPS-N. The emission signature of Fe is detected with both instruments at significance levels of 5.7σ and 4.5σ, respectively. By combining all observations, we obtain a significance level of 7.3σ for Fe. We find the TiO signal at Kp = 248.0-2.5+2.0 km s-1, which is in disagreement with the Fe detection at Kp = 225.0-3.5+4.0 km s-1. The Kp value for Fe is in agreement with prior investigations. The model spectra require different temperature profiles for TiO and Fe to match the observations. We observe a broader line profile for Fe than for TiO. Conclusions. Our results confirm the existence of a temperature inversion layer in the planetary atmosphere. The observed Kp offset and different strengths of broadening in the line profiles suggest the existence of a TiO-depleted hot spot in the planetary atmosphere. © ESO 2021. ; CARMENES is an instrument at the Centro Astronomico Hispano-Aleman (CAHA) at Calar Alto (Almeria, Spain), operated jointly by the Junta de Andalucia and the Instituto de Astrofisica de Andalucia (CSIC). CARMENES was funded by the Max-Planck-Gesellschaft (MPG), the Consejo Superior de Investigaciones Cientificas (CSIC), the Ministerio de Economia y Competitividad (MINECO) and the European Regional Development Fund (ERDF) through projects FICTS-2011-02, ICTS-2017-07-CAHA-4, and CAHA16-CE-3978, and the members of the CARMENES Consortium (Max-Planck-Institut fur Astronomie, Instituto de Astrofisica de Andalucia, Landessternwarte Konigstuhl, Institut de Ciencies de l'Espai, Institut fur Astrophysik Gottingen, Universidad Complutense de Madrid, Thuringer Landessternwarte Tautenburg,Instituto de Astrofisica de Canarias, Hamburger Sternwarte, Centro de Astrobiologia and Centro Astronomico Hispano-Aleman), with additional contributions by the MINECO, the Deutsche Forschungsgemeinschaft through the Major Research Instrumentation Programme and Research Unit FOR2544 "Blue Planets around Red Stars", the Klaus Tschira Stiftung, the states of Baden-Wurttemberg and Niedersachsen, and by the Junta de Andalucia. We acknowledge financial support from the Deutsche Forschungsgemeinschaft through the priority program SPP 1992 "Exploring the Diversity of Extrasolar Planets" (RE 1664/16-1), the Research Unit FOR2544 "Blue Planets around Red Stars" (RE 1664/21-1), and grant CA 1795/3, the Agencia Estatal de Investigacion of the Ministerio de Ciencia, Innovacion y Universidades and the ERDF through projects PID2019-109522GB-C5[1:4]/AEI/10.13039/501100011033, PID2019-110689RB-I00/AEI/10.13039/501100011033, and the Centre of Excellence "Severo Ochoa" and "Maria de Maeztu" awards to the Instituto de Astrofisica de Canarias (SEV-2015-0548), Instituto de Astrofisica de Andalucia (SEV-2017-0709), and Centro de Astrobiologia (MDM-2017-0737), the European Research Council under the European Union's Horizon 2020 research and innovation program (832428), and the Generalitat de Catalunya/CERCA programme. This work is based on observations made with the Italian Telescopio Nazionale Galileo (TNG) operated on the island of La Palma by the Fundacion Galileo Galilei of the INAF (Istituto Nazionale di Astrofisica) at the Spanish Observatorio del Roque de los Muchachos of the Instituto de Astrofisica de Canarias. ; Peer reviewed

Ultra-hot Jupiters (UHJs) are highly irradiated giant exoplanets with extremely high day-side temperatures, which lead to thermal dissociation of most molecular species. It is expected that the neutral hydrogen atom is one of the main species in the upper atmospheres of UHJs. Neutral hydrogen has been detected in several UHJs by observing their Balmer line absorption. In this work, we report four transit observations of the UHJ WASP-33b, performed with the CARMENES and HARPS-North spectrographs, and the detection of the Hα, Hβ, and Hγ lines in the planetary transmission spectrum. The combined Hα transmission spectrum of the four transits has an absorption depth of 0.99 ± 0.05%, which corresponds to an effective radius of 1.31 ± 0.01 Rp. The strong Hα absorption indicates that the line probes the high-altitude thermosphere. We further fitted the three Balmer lines using the PAWN model, assuming that the atmosphere is hydrodynamic and in local thermodynamic equilibrium. We retrieved a thermosphere temperature 12 200-1000+1300 K and a mass-loss rate ? = 1011.8-0.5+0.6 g s-1. The retrieved high mass-loss rate is compatible with the "Balmer-driven"atmospheric escape scenario, in which the stellar Balmer continua radiation in the near-ultraviolet is substantially absorbed by excited hydrogen atoms in the planetary thermosphere. © ESO 2020. ; We thank the referee for the useful comments. F.Y. acknowledges the support of the DFG priority program SPP 1992 "Exploring the Diversity of Extrasolar Planets (RE 1664/16-1)". CARMENES is an instrument for the Centro Astronomico Hispano-Aleman (CAHA) at Calar Alto (Almeria, Spain), operated jointly by the Junta de Andalucia and the Instituto de Astrofisica de Andalucia (CSIC). CARMENES was funded by the MaxPlanck-Gesellschaft (MPG), the Consejo Superior de Investigaciones Cientificas (CSIC), the Ministerio de Economia y Competitividad (MINECO) and the European Regional Development Fund (ERDF) through projects FICTS-2011-02, ICTS-2017-07-CAHA-4, and CAHA16-CE-3978, and the members of the CARMENES Consortium (Max-Planck-Institut fur Astronomie, Instituto de Astrofisica de Andalucia, Landessternwarte Konigstuhl, Institut de Ciencies de l'Espai, Institut fur Astrophysik Gottingen, Universidad Complutense de Madrid, Thuringer Landessternwarte Tautenburg, Instituto de Astrofisica de Canarias, Hamburger Sternwarte, Centro de Astrobiologia and Centro Astronomico Hispano-Aleman), with additional contributions by the MINECO, the Deutsche Forschungsgemeinschaft through the Major Research Instrumentation Programme and Research Unit FOR2544 "Blue Planets around Red Stars", the Klaus Tschira Stiftung, the states of Baden-Wurttemberg and Niedersachsen, and by the Junta de Andalucia. Based on data from the CARMENES data archive at CAB (CSIC-INTA). We acknowledge financial support from the Agencia Estatal de Investigacion of the Ministerio de Ciencia, Innovacion y Universidades and the ERDF through projects PID2019-109522GB-C51/2/3/4, PGC2018-098153-B-C33, AYA2016-79425-C3-1/2/3-P, ESP2016-80435-C2-1-R and the Centre of Excellence "Severo Ochoa" and "Maria de Maeztu" awards to the Instituto de Astrofisica de Canarias (SEV-2015-0548), Instituto de Astrofisica de Andalucia (SEV-2017-0709), and Centro de Astrobiologia (MDM-2017-0737), and the Generalitat de Catalunya/CERCA programme. A.W. acknowledges the financial support of the SNSF by grant number P400P2_186765. P.M. acknowledges support from the European Research Council under the Horizon 2020 Framework Program via ERC grant 832428. I.S. acknowledges funding from the European Research Council (ERC) under the European Union's Horizon 2020 research and innovation program under grant agreement No 694513. M.L. achkowledges the funding from the project ESP2017-87143-R. This work is based on observations made with the Italian Telescopio Nazionale Galileo (TNG) operated on the island of La Palma by the Fundacion Galileo Galilei of the INAF (Istituto Nazionale di Astrofisica) at the Spanish Observatorio del Roque de los Muchachos of the Instituto de Astrofisica de Canarias. ; Peer reviewed

Ultra-hot Jupiters (UHJs) are gas giants with very high equilibrium temperatures. In recent years, multiple chemical species, including various atoms and ions, have been discovered in their atmospheres. Most of these observations have been performed with transmission spectroscopy, although UHJs are also ideal targets for emission spectroscopy due to their strong thermal radiation. We present high-resolution thermal emission spectroscopy of the transiting UHJ KELT-20b/MASCARA-2b. The observation was performed with the CARMENES spectrograph at orbital phases before and after the secondary eclipse. We detected atomic Fe using the cross-correlation technique. The detected Fe lines are in emission, which unambiguously indicates a temperature inversion on the dayside hemisphere. We furthermore retrieved the temperature structure with the detected Fe lines. The result shows that the atmosphere has a strong temperature inversion with a temperature of 4900 ± 700 K and a pressure of 10−4.8−1.1+1.0 bar at the upper layer of the inversion. A joint retrieval of the CARMENES data and the TESS secondary eclipse data returns a temperature of 2550−250+150 K and a pressure of 10−1.5−0.6+0.7 bar at the lower layer of the temperature inversion. The detection of such a strong temperature inversion is consistent with theoretical simulations that predict an inversion layer on the dayside of UHJs. The joint retrieval of the CARMENES and TESS data demonstrates the power of combing high-resolution emission spectroscopy with secondary eclipse photometry in characterizing atmospheric temperature structures. © ESO 2022. ; F.Y. acknowledges the support of the DFG Research Unit FOR2544 "Blue Planets around Red Stars" (RE 1664/21-1). CARMENES is an instrument for the Centro Astronómico Hispano-Alemán (CAHA) at Calar Alto (Almería, Spain), operated jointly by the Junta de Andalucía and the Instituto de Astrofísica de Andalucía (CSIC). CARMENES was funded by the Max-Planck-Gesellschaft (MPG), the Consejo Superior de Investigaciones Científicas (CSIC), the Ministerio de Economía y Competitividad (MINECO) and the European Regional Development Fund (ERDF) through projects FICTS-2011-02, ICTS-2017-07-CAHA-4, and CAHA16-CE-3978, and the members of the CARMENES Consortium (Max-Planck-Institut für Astronomie, Instituto de Astrofísica de Andalucía, Landessternwarte Königstuhl, Institut de Ciències de l'Espai, Institut für Astrophysik Göttingen, Universidad Complutense de Madrid, Thüringer Landessternwarte Tautenburg, Instituto de Astrofísica de Canarias, Hamburger Sternwarte, Centro de Astrobiología and Centro Astronómico Hispano-Alemán), with additional contributions by the MINECO, the Deutsche Forschungsgemeinschaft through the Major Research Instrumentation Programme and Research Unit FOR2544 "Blue Planets around Red Stars", the Klaus Tschira Stiftung, the states of Baden-Württemberg and Niedersachsen, and by the Junta de Andalucía. Based on data from the CARMENES data archive at CAB (CSIC-INTA). We acknowledge financial support from the Agencia Estatal de Investigación of the Ministerio de Ciencia, Innovación y Universidades and the ERDF through projects PID2019-109522GB-C51/2/3/4, PGC2018-098153-B-C33, AYA2016-79425-C3-1/2/3-P, ESP2016-80435-C2-1-R and the Centre of Excellence "Severo Ochoa" and "María de Maeztu" awards to the Instituto de Astrofísica de Canarias (SEV-2015-0548), Instituto de Astrofísica de Andalucía (SEV-2017-0709), and Centro de Astrobiología (MDM-2017-0737), and the Generalitat de Catalunya/CERCA programme. T.H. and P.M. acknowledge support from the European Research Council under the Horizon 2020 Framework Program via the ERC Advanced Grant Origins 83 24 28. N.C. and A.S.L. acknowledge funding from the European Research Council under the European Union's Horizon 2020 research and innovation program under grant agreement no. 694513. ; Peer reviewed