Suchergebnisse

[EN] This study focused on the effect of salinity on the performance of a pilot-scale nanofiltration (NF) for preconcentration of microcontaminants (MCs) in combination with solar photo-Fenton or photo-Fenton-like treatment for their elimination from NF permeate and concentrate streams. Photo-Fenton was carried out in a solar simulator at pH of 3 and at natural pH using Ethylenediamine-N, N'-disuccinic acid (EDDS) as an iron complexing agent Degradation efficacy was tested with MCs commonly found in urban wastewater treatment plant effluents (caffeine, imidacloprid, thiacloprid, carbamazepine and diclofenac). Hydrogen peroxide and persulfate were compared in solar processes. Increase in salinity and pressure had a negligible influence on MC permeability order and NF selectivity. Solar photo-Fenton was able to degrade MCs present in the concentrated stream, and rapidly eliminate any residual MCs that might finally be present in permeate streams. Persulfate used instead of hydrogen peroxide was shown to be inefficient for the selected MCs. Fe(Ill):EDDS at circumneutral pH was able to remove MCs as quickly as classical photo-Fenton at acid pH, or even faster. This effect supports use of Fe(III):EDDS at natural pH for treating NF concentrates or polishing NF permeates when NF membranes are operated under extreme conditions of salinity. ; This paper is part of a project that received funding from the European Union's Horizon 2020 Research and Innovation Programme under Marie Sklodowska-Curie Grant Agreement No 765860. Dennis Deemter would like to thank the staff at the Plataforma Solar de Almeria. The authors wish to thank the Spanish Ministry of Science, Innovation and Universities (MCIU), AEI and FEDER for funding under the CalypSol Project (Reference: RTI2018-097997-B-C32 and RTI2018097997-B-C31). ; Deemter, D.; Oller, I.; Amat Payá, AM.; Malato, S. (2021). Effect of salinity on preconcentration of contaminants of emerging concern by nanofiltration: Application of solar photo-Fenton as a tertiary treatment. ...

AbstractThe increasing occurrence of micropollutants in natural water bodies has medium to long-term effects on both aquatic life and human health. The aim of this study is to optimize the degradation of two pharmaceutical pollutants of emerging concern: amoxicillin and acetaminophen in aqueous solution at laboratory and pilot scale, by solar photo-Fenton process carried out at neutral pH using ethylenediamine-N,N′-disuccinic acid (EDDS) as a complexing agent to maintain iron in solution. The initial concentration of each compound was set at 1 mg/L dissolved in a simulated effluent from a municipal wastewater treatment plant (MWTP). A factorial experimental design and its surface response analysis were used to optimize the operating parameters to achieve the highest initial degradation rate of each target. The evolution of the degradation process was measured by ultra-performance liquid chromatography (UPLC/UV), obtaining elimination rates above 90% for both contaminants. Statistical study showed the optimum concentrations of Fe(III) at 3 mg/L at an Fe-EDDS ratio of 1:2 and 2.75 mg/L H2O2 for the almost complete removal of the target compounds by solar photo-Fenton process. Validation of the experimental design was successfully carried out with actual MWTP effluent spiked with 100 μg/L of amoxicillin and acetaminophen, each at pilot plant scale.

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) ; Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) ; Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) ; Spanish Ministry of Education ; Andalusia Regional Government ; Spanish Ministry of Education: CSD2006-00044 ; Andalusia Regional Government: P06-TEP-02329 ; The influence of iron species on amoxicillin (AMX) degradation, intermediate products generated and toxicity during the photo-Fenton process using a solar simulator were evaluated in this work. The AMX degradation was favored in the presence of the potassium ferrioxalate complex (FeOx) when compared to FeSO(4). Total oxidation of AMX in the presence of FeOx was obtained after 5 min, while 15 min were necessary using FeSO4. The results obtained with Daphnia magna biossays showed that the toxicity decreased from 65 to 5% after 90 min of irradiation in the presence of FeSO(4). However, it increased again to a maximum of 100% after 150 min, what indicates the generation of more toxic intermediates than AMX, reaching 45% after 240 min. However, using FeOx, the inhibition of mobility varied between 100 and 70% during treatment, probably due to the presence of oxalate, which is toxic to the neonates. After 240 min, between 73 and 81% TOC removal was observed. Different pathways of AMX degradation were suggested including the opening of the four-membered beta-lactamic ring and further oxidations of the methyl group to aldehyde and/or hydroxylation of the benzoic ring, generating other intermediates after bound cleavage between different atoms and further oxidation to carboxylates such acetate, oxalate and propionate, besides the generation of nitrate and ammonium. (C) 2010 Elsevier Ltd. All rights reserved.