Suchergebnisse

Development of a method of formation of chiral free-standing films from carbon nanotubes (CNTs), which circumvents the limitations of the established techniques, is presented. CNT macroassemblies of any size and shape can be made from desired CNT feed including those synthesized or sorted with the objective of chirality control. Free-standing CNT films were created from various starting CNT materials the most interesting being of predominantly (6,5) and (7,6) chirality. The technique offers the advantages of technical simplicity, scalability and non-destructive nature representing an important step toward the research, development and implementation of monochiral single-wall CNT tangible objects. ; The European Research Council (Grant Agreement - 259061). National Science Center, Poland (Grant Agreement - UMO-2015/19/P/ST5/03799). The European Union's Horizon 2020 research and innovation programme (Grant Agreement - 665778).

We have demonstrated fire-retardancy properties of a polymer matrix-free CNT film for the first time. As compared with classical fire-retardant materials such as Kevlar, Twaron or Nomex, the CNT film showed a spectrum of advantages. The material is lightweight, flexible and well-adherent to even the most complicated shapes. The results have showed that by using CNTs for fire-retardancy we can extend the operational time almost two-fold, what makes CNTs a much better protection than the solutions employed nowadays. We believe that among other great properties of CNT, their macroscopic assemblies such as CNT films show significant potential for becoming a fire protective coating, which exhibits high performance in not sustaining fire. ; The European Research Council (Grant Agreement - 259061). National Science Center, Poland (Grant Agreement - UMO-2015/19/P/ST5/03799). The European Union's Horizon 2020 research and innovation programme (Grant Agreement - 665778).

We report on the development of a method of formation of free-standing gold-carbon nanotube (CNT) composites. It is based on a quick and simple decoration of CNT films with the application of chloroauric aqueous solution. Flexible and conductive macroassemblies of any size and shape can be created with ease. Addition of as little as 1% of Au by weight allowed for reduction of resistance by more than a quarter. Higher Au doping resulted in further decrease of resistance, but not so significant. From the practical point of view, these composites are a new type of materials with high electrical conductivity, but also offer resistance to corrosion. ; The European Research Council (Grant Agreement - 259061). National Science Center, Poland (Grant Agreement - UMO-2015/19/P/ST5/03799). The European Union's Horizon 2020 research and innovation programme (Grant Agreement - 665778).

The electronic properties of carbon nanostructures such as carbon nanotubes (CNTs) or graphene can easily be tuned by the action of various doping agents. We present an experimental study and numerical analysis of how and why metallic and semiconductive CNTs can be p-doped by exposing them to two interhalogens: iodine monochloride and iodine monobromide. Simple application of these compounds was found to reduce the electrical resistance by as much as 2/3 without causing any unfavorable chemical modification, which could disrupt the highly conductive network of sp2 carbon atoms. To gain better insight into the underlying mechanism of the observed experimental results, we provide a first principles indication of how interhalogens interact with model metallic (5,5) and semiconductive (10,0) CNTs. ; The European Research Council (Grant Agreement - 259061). The Interdisciplinary Centre for Mathematical and Computational Modelling at the University of Warsaw (Grant Agreement - G47-5). National Science Center, Poland (Grant Agreement - UMO-2015/19/P/ST5/03799). The European Union's Horizon 2020 research and innovation programme (Grant Agreement - 665778).