Suchergebnisse

The helium coolant in the primary circuit of the high-temperature gas-cooled reactor (HTGR) contains traces of impurities, which can induce the corrosion of superalloys when exposed to elevated temperatures. The superalloy damage caused by the corrosion could threaten the safe operation of the reactor. In this work, the corrosion behavior of a representative superalloy (chromium-rich iron base alloy Incoloy 800H) was investigated under the impure helium at different typical temperatures of HTGR. An experimental setup developed for studying the high-temperature corrosion of superalloys was used to investigate the chemical reactions and corrosion behaviors of Incoloy 800H. It was found that CO2 is an important oxygen source in the reaction with chromium, and CO is released as the product. In addition, the observation and computation of the critical temperature (TC) of the reaction between CO2 and carbon in the alloy show that TC is much lower than that (TA) of the microclimate reaction, which indicates that CO2 can protect the scale from destruction. Furthermore, the slight decarbonization of the alloy was found above TC. Also, a model developed by the thermodynamic analysis was proposed to explain the mechanism of slight decarbonization and predict the critical temperature when the CO2-C reaction occurs. This work presents a guideline for protecting the oxide scale of superalloys used in HTGR.

Many tons of porous carbon materials (including BC and IG-110) are contained in HTGR, which are serving as structural material and fuel matrix material. These materials would absorb moisture and other impurities when exposed to the environment, and these impurities (especially moisture) absorbed in the carbon material must be removed before the reactor operation to prevent corrosion reaction at high temperature (more than 500°C). As the pore microscopic structure characteristic is the significant factor affecting the gas adsorption and flow in the porous materials, the detailed 3D pore structures of the carbon materials (BC and IG-110) in HTGR were studied by Micro-XCT and HPMI methods in this paper. These pore structure characteristics include pore geometry, pore size distribution, and pore throat connectivity. The test results show that the pore size distribution of BC material is wide, and the pore diameter is obviously larger than that of IG-110. Pore connections in BC show radial shape connections at some special points, and the pore connectivity in IG-110 is very complex and presents a huge complex 3D pore network.

A large number of carbon materials are adopted in high-temperature gas-cooled reactor (HTGR). These carbon materials mainly include graphite IG-110 and boron-containing carbon material (BC), both of which are typical porous materials and normally absorb moisture. In order to inhibit the chemical corrosion reaction between core internals materials and moisture, the core needs to be strictly dehumidified before the reactor is put into operation. This paper mainly analyzed the moisture transfer mechanism in these carbon materials. Moisture transfer models were developed, and the dehumidification process of HTR-PM core was simulated. In addition, the influence of working temperature and system pressure on dehumidification was studied as well.