Suchergebnisse

1 Introduction -- References -- 2 Lead in the atmosphere -- 2.1 Introduction -- 2.2 Sources of lead in air -- 2.3 Concentrations of lead in ambient air -- 2.4 Particle size distributions -- 2.5 Chemical properties of atmospheric lead -- References -- 3 Lead in water -- 3.1 Introduction -- 3.2 Sources of lead in surface waters -- 3.3 Concentrations of lead in water -- 3.4 Chemistry of lead in water -- References -- 4 Lead in soils -- 4.1 Introduction -- 4.2 Sources of lead in soil -- 4.3 Concentrations of lead in soil -- 4.4 Uptake of soil lead by living organisms -- 4.5 Chemistry of lead in soils -- 4.6 Lead in street dusts -- References -- 5 Control of lead in air -- 5.1 Industrial sources of lead -- 5.2 Control of industrial emissions of lead -- 5.3 Legislative regulations affecting industrial lead emissions -- 5.4 Control of lead emissions from motor vehicles -- 5.5 Ambient air quality standard for lead -- 5.6 Control of lead within the workplace -- References -- 6 Control of lead discharges to water -- 6.1 Introduction -- 6.2 Water quality criteria and standards -- 6.3 Uniform emission standards versus water quality objectives -- 6.4 Control practices for lead discharges -- References -- 7 Human exposure to lead and its effects -- 7.1 Introduction -- 7.2 Sources and intake of lead -- 7.3 Uptake of lead -- 7.4 Metabolism of lead -- 7.5 Blood leads -- 7.6 Biological and adverse health effects of exposure to lead -- References -- 8 Chemical analysis of lead in the environment -- 8.1 Introduction -- 8.2 Chemical analysis of lead: available techniques -- 8.3 Sampling and analysis of environmental media -- 8.4 Contamination during lead analysis -- References.

The international airport of Heathrow is a major source of nitrogen oxides, but its contribution to the levels of sub-micrometre particles is unknown and is the objective of this study. Two sampling campaigns were carried out during warm and cold seasons at a site close to the airfield (1.2 km). Size spectra were largely dominated by ultrafine particles: nucleation particles ( < 30 nm) were found to be ∼ 10 times higher than those commonly measured in urban background environments of London. Five clusters and six factors were identified by applying k means cluster analysis and positive matrix factorisation (PMF), respectively, to particle number size distributions; their interpretation was based on their modal structures, wind directionality, diurnal patterns, road and airport traffic volumes, and on the relationship with weather and other air pollutants. Airport emissions, fresh and aged road traffic, urban accumulation mode, and two secondary sources were then identified and apportioned. The fingerprint of Heathrow has a characteristic modal structure peaking at < 20 nm and accounts for 30–35 % of total particles in both the seasons. Other main contributors are fresh (24–36 %) and aged (16–21 %) road traffic emissions and urban accumulation from London (around 10 %). Secondary sources accounted for less than 6 % in number concentrations but for more than 50 % in volume concentration. The analysis of a strong regional nucleation event showed that both the cluster categorisation and PMF contributions were affected during the first 6 h of the event. In 2016, the UK government provisionally approved the construction of a third runway; therefore the direct and indirect impact of Heathrow on local air quality is expected to increase unless mitigation strategies are applied successfully.

ABSTRACTThis paper presents data on the distribution of seven pesticides in an agricultural catchment which is located within the Agricultural Development and Advisory Service farm at Rosemaund, 11 km north‐east of Hereford, UK. Data for aldicarb, atrazine, carbofuran, dimethoate, MCPA and isoproturon, are available for both the soil and surface waters (drain and stream water), with simazine data available only for the stream. Measurements were taken before and after pesticide application, which was made following normal agricultural practice. Soil residue data showed the degradation rates of the pesticides to be within the range of literature values. Pesticide levels in the stream and drains during runoff events following rainfall ranged from below detection limits (typically 0.02‐0.1 μg/1), to 264 μg/1 (for carbofuran). Over 90% of the events had detectable maximum concentrations. The percentage of pesticide applied, which was removed during individual rainfall events, was calculated. The maximum value estimated was 1.1%, again for carbofuran. Most of the events gave values several orders of magnitude below this value.The data have been used to try to validate a range of models which could be used for screening new pesticides or for informing decisions on the use of existing pesticides. The results of the validations are summarized.

AbstractData are presented on four pesticides applied to agricultural land at the Agricultural Development Advisory Service, Rosemaund, in the west of England. The farm covers a well‐defined and isolated water basin of cracking heavy clay loam soils drained by a single stream. Levels of the relatively particle‐bound pesticides trifluralin, deltamethrin, chlorpyrifos and fenpropimorph were measured in drainage water and field soils following application. Observed concentrations in water were generally below 1 μg/l with occasional peak levels exceeding 10 μg/l during storm rainfall events. Unexpectedly high peak levels of deltamethrin of around 2 μg/l highlighted significant bypass flow mechanisms from the surface soils during the autumn. Additional bioassay experiments showed that levels of chlorpyrifos, lethal to Gammarus pulex, reached the stream during spring 1993. The Rosemaund farm has been the site of a continuing investigation into the movement of agricultural pesticides to surface waters since 1987, and this report represents the final work conducted in the autumn of 1992 and spring 1993.

Solid fuel emissions, including those from biomass burning, are increasing in urban areas across the European Union due to rising energy costs and government incentives to use renewable energy sources for heating. In order to help protect human health as well as to improve air quality and pollution abatement strategies, the sources of combustion aerosols, their contributions, and the processes they undergo need to be better understood. A high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) was therefore deployed at an urban background site between January and February 2012 to investigate solid fuel organic aerosols (SFOA) in London. The variability of SFOA was examined and the factors governing the split between the two SFOA factors derived from Positive Matrix Factorisation (PMF) were assessed. The concentrations of both factors were found to increase during the night and during cold periods, consistent with domestic space heating activities. The split between the two factors is likely governed predominantly by differences in burn conditions where SFOA1 best represents more efficient burns and SFOA2 best represents less efficient burns. The differences in efficiency may be due to burner types or burn phase, for example. Different fuel types and levels of atmospheric processing also likely contribute to the two factors. As the mass spectral profile of SFOA is highly variable, the findings from this study may have implications for improving future source apportionment and factorisation analyses. During the winter, SFOA was found to contribute 38% to the total non-refractory submicron organic aerosol (OA) mass, with similar contributions from both SFOA factors (20% from SFOA1 and 18% from SFOA2). A similar contribution of SFOA was derived for the same period from a compact time-of-flight AMS (cToF-AMS), which measured for a full calendar year at the same site. The seasonality of SFOA was investigated using the year-long data set where concentrations were greatest in the autumn and winter. During the summer, SFOA contributed 11% to the organic fraction, where emissions resulted from different anthropogenic activities such as barbecues and domestic garden wood burning. The significant contribution of SFOA to total organic mass throughout the year suggests that the negative effects on health and air quality, as well as climate, are not just confined to winter as exposure to these aerosols and the associated black carbon can also occur during the summer, which may have significant implications for air-quality policies and mitigation strategies.

Solid fuel emissions, including those from biomass burning, are increasing in urban areas across the European Union due to rising energy costs and government incentives to use renewable energy sources for heating. In order to help protect human health as well as to improve air quality and pollution abatement strategies, the sources of combustion aerosols, their contributions, and the processes they undergo need to be better understood. A high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) was therefore deployed at an urban background site between January and February 2012 to investigate solid fuel organic aerosols (SFOA) in London. The variability of SFOA was examined and the factors governing the split between the two SFOA factors derived from Positive Matrix Factorisation (PMF) were assessed. The concentrations of both factors were found to increase during the night and during cold periods, consistent with domestic space heating activities. The split between the two factors is likely governed predominantly by differences in burn conditions where SFOA1 best represents more efficient burns and SFOA2 best represents less efficient burns. The differences in efficiency may be due to burner types or burn phase, for example. Different fuel types and levels of atmospheric processing also likely contribute to the two factors. As the mass spectral profile of SFOA is highly variable, the findings from this study may have implications for improving future source apportionment and factorisation analyses. During the winter, SFOA was found to contribute 38% to the total non-refractory submicron organic aerosol (OA) mass, with similar contributions from both SFOA factors (20% from SFOA1 and 18% from SFOA2). A similar contribution of SFOA was derived for the same period from a compact time-of-flight AMS (cToF-AMS), which measured for a full calendar year at the same site. The seasonality of SFOA was investigated using the year-long data set where concentrations were greatest in the autumn and winter. During the summer, SFOA contributed 11% to the organic fraction, where emissions resulted from different anthropogenic activities such as barbecues and domestic garden wood burning. The significant contribution of SFOA to total organic mass throughout the year suggests that the negative effects on health and air quality, as well as climate, are not just confined to winter as exposure to these aerosols and the associated black carbon can also occur during the summer, which may have significant implications for air-quality policies and mitigation strategies.

Solid fuel emissions, including those from biomass burning, are increasing in urban areas across the European Union due to rising energy costs and government incentives to use renewable energy sources for heating. In order to help protect human health as well as to improve air quality and pollution abatement strategies, the sources of combustion aerosols, their contributions, and the processes they undergo need to be better understood. A high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) was therefore deployed at an urban background site between January and February 2012 to investigate solid fuel organic aerosols (SFOA) in London. The variability of SFOA was examined and the factors governing the split between the two SFOA factors derived from Positive Matrix Factorisation (PMF) were assessed. The concentrations of both factors were found to increase during the night and during cold periods, consistent with domestic space heating activities. The split between the two factors is likely governed predominantly by differences in burn conditions where SFOA1 best represents more efficient burns and SFOA2 best represents less efficient burns. The differences in efficiency may be due to burner types or burn phase, for example. Different fuel types and levels of atmospheric processing also likely contribute to the two factors. As the mass spectral profile of SFOA is highly variable, the findings from this study may have implications for improving future source apportionment and factorisation analyses. During the winter, SFOA was found to contribute 38% to the total non-refractory submicron organic aerosol (OA) mass, with similar contributions from both SFOA factors (20% from SFOA1 and 18% from SFOA2). A similar contribution of SFOA was derived for the same period from a compact time-of-flight AMS (cToF-AMS), which measured for a full calendar year at the same site. The seasonality of SFOA was investigated using the year-long data set where concentrations were greatest in the autumn and winter. During the summer, SFOA contributed 11% to the organic fraction, where emissions resulted from different anthropogenic activities such as barbecues and domestic garden wood burning. The significant contribution of SFOA to total organic mass throughout the year suggests that the negative effects on health and air quality, as well as climate, are not just confined to winter as exposure to these aerosols and the associated black carbon can also occur during the summer, which may have significant implications for air-quality policies and mitigation strategies.

This exciting book gives an overview of environmental forensics and related topics with contributions from worldwide experts, 'Environmental forensics' is a combination of analytical and environmental chemistry, which is useful in the court room context. It therefore involves field analytical studies and both data interpretation and modelling connected with the attribution of pollution events to their causes. Recent decades have seen a burgeoning of legislation designed to protect the environment and, as the costs of environmental damage and clean-up are considerable, not only are there prosecutions by regulatory agencies, but the courts are also used as a means of adjudication of civil damage claims relating to environmental causes or environmental degradation. As a result is the increasing number of prosecutions of companies who have breached regulations for environmental protection and in civil claims relating to harm caused by excessive pollutant releases to the environment. Such cases can become extremely protracted as expert witnesses provide their sometimes conflicting interpretations of environmental measurement data and their meaning. It is in this context that environmental forensics is developing as a specialism, leading to greater formalisation of investigative methods which should lead to more definitive findings and less scope for experts to disagree. Now a significant subject in its own right, at least one journal devoted to the field and a number of degree courses have sprung up. As a result of the topicality and rapid growth of the subject area, is the publication of this book - the 26th volume in the highly acclaimed Issues in Environmental Science and Technology Series. This volume contains authoritative articles by a number of the leading practitioners across the globe in the environmental forensics field and aims to cover some of the main techniques and areas to which environmental forensics are being applied. The content is comprehensive and describes a number of the key areas within environmental forensics - topics covered by the authors include: - Source identification issues - Microbial techniques - Metal contamination and methods of assigning liability - The use of isotopes to determine sources and their applications - Molecular biological methods - Hydrocarbon fingerprinting techniques - Oil chemistry and key compound identification - The emerging role of environmental forensics in groundwater pollution Additionally, the volume considers specific pollutants and long-lived pollutants of groundwater such as halocarbons which have presented particular problems and which are described in some depth, as well as the way in which chemical degradation processes can lead to compositional changes which provide valuable information. The book provides a comprehensive overview of many of the key areas of environmental forensics written by some of the leading experts in the field. It will be both of specialist use to those seeking expert insights into the field and its capabilities as well as of more general interest to those involved in both environmental analytical science and environmental law