Suchergebnisse

This book details the experiences gained by the Catalan Water Agency (ACA) in a Mediterranean watershed - the Catalan River Basin District - following the launch of the EU Water Framework Directive (WFD) in the year 2000. Experts in rivers, reservoirs, lakes, wetlands and estuaries present 13 chapters defining tools for water-status assessment specially adapted to Mediterranean conditions. The content of this and the companion volume Experiences from Ground, Coastal and Transitional Water Quality Monitoring: The EU Water Framework Directive Implementation in the Catalan River Basin District (Part II) are the result of an excellent collaboration between the ACA and several Catalan universities and research centers to cope with new challenges provided by the WFD monitoring requirements. The volume serves as a useful guide for environmental managers and scientists engaged in other European as well as Non-European river basins

This book details the experiences gained by the Catalan Water Agency (ACA) in a Mediterranean watershed - the Catalan River Basin District - following the launch of the EU Water Framework Directive (WFD) in the year 2000. Groundwater and coastal water experts present 13 chapters defining tools for water-status assessment specially adapted to Mediterranean conditions. The content of this and the companion volume Experiences from Surface Water Quality Monitoring: The EU Water Framework Directive Implementation in the Catalan River Basin District (Part I) are the result of an excellent collaboration between the ACA and several Catalan universities and research centers to cope with new challenges provided by the WFD monitoring requirements. The volume serves as a useful guide for environmental managers and scientists engaged in other European as well as Non-European river basins

Intro -- The Llobregat: The Story of a Polluted Mediterranean River -- The Handbook of Environmental Chemistry Also Available Electronically -- Aims and Scope -- Series Preface -- Volume Preface -- Contents -- The Llobregat River Basin: A Paradigm of Impaired Rivers Under Climate Change Threats -- 1 The Llobregat River Basin -- 1.1 Geology -- 1.2 Vegetation -- 1.3 Climate -- 1.4 Hydrological Alterations due to Global Change -- 2 A Historical Perspective on Human Exploitation of the River -- 2.1 Early Uses: The Feared River -- 2.2 Bridging the River -- 2.3 Approaching the River: Mills and Irrigation -- 2.4 River Industries -- 2.5 Dams -- 2.6 Water Pollution and Salinity Conflict -- 3 The Llobregat as an Overexploited River: Interconnectivity in the Llobregat Basin and the Urban Loop -- References -- Low Llobregat Aquifers: Intensive Development, Salinization, Contamination, and Management -- 1 Introduction -- 2 Hydrogeological Characteristics of the Low Llobregat Area -- 3 Groundwater Development -- 4 Hydrogeological Conceptual Model Under Natural Conditions -- 5 Hydrogeological Conceptual Model Under Disturbed Conditions -- 6 Hydrogeochemistry and Mass Transport -- 7 Groundwater Contamination -- 8 Groundwater Management in the Low Llobregat Aquifer System -- 9 Concluding Remarks -- References -- Managed Artificial Recharge in the Llobregat Aquifers: Quantitative Versus Qualitative Aspects -- 1 Introduction -- 1.1 The Need for MAR into the Llobregat River Aquifers -- 1.2 A Summary of Managed Artificial Recharge Practices: Objectives and Methodologies -- 2 Scarification Activities at the Riverbed (Lower Valley) -- 3 Deep Injection from Drinking Water Quality Surpluses (Delta) -- 4 Surface Ponds in Castellbisbal (St. Andreu Basin) -- 5 Surface Ponds in Sant Vicenç dels Horts (Lower Valley).

River ecosystems are subject to multiple stressors that affect their structure and functioning. Ecosystem structure refers to characteristics such as channel form, water quality or the composition of biological communities, whereas ecosystem functioning refers to processes such as metabolism, organic matter decomposition or secondary production. Structure and functioning respond in contrasting and complementary ways to environmental stressors. Moreover, assessing the response of ecosystem functioning to stressors is critical to understand the effects on the ecosystem services that produce direct benefits to humans. Yet, there is more information on structural than on functional parameters, and despite the many approaches available to measure river ecosystem processes, structural approaches are more widely used, especially in management. One reason for this discrepancy is the lack of synthetic studies analyzing river ecosystem functioning in a way that is useful for both scientists and managers. Here, we present a synthesis of key river ecosystem processes, which provides a description of the main characteristics of each process, including criteria guiding their measurement as well as their respective sensitivity to stressors. We also discuss the current limitations, potential improvements and future steps that the use of functional measures in rivers needs to face. © 2017 The Author(s) ; This work has been supported by the EU 7th Framework Programme Funding under Grant agreement no. 603629-ENV-2013-6.2.1-Globaqua. Additional financial support has been provided by the Basque Government under Grant agreement no. IT951-16. We also acknowledge financial support in terms of pre-doctoral and post-doctoral grants from the University of the Basque Country (O. Pereda, L. Solagaistua, I. Aristi, M. Arroita, A. Martínez) and from the Spanish Ministry of Economy and Competitiveness (S. Monroy). ; Peer reviewed

In this paper, we build a preliminary inventory of dissolved phase water emissions of 36 of the 45 chemical priority substances under the European Union's Water Framework Directive. For point sources, we consider the European Pollutant Release and Transfer Register (E-PRTR) containing reported emissions from major industrial facilities. We consider all other sources as diffuse, and we estimate European average chemical emission factors from available measurements of dissolved phase concentrations, assuming simple emission patterns such as population and agricultural land. The emission inventory enables modelling concentrations, which have been compared with independent measurements. Due to the way they are estimated, they cannot withstand a point-by-point comparison. However, predicted concentrations exhibit a frequency distribution and order of magnitude compatible with observations, and match a fair proportion of independently reported exceedances of environmental quality standards for many of the substances studied. While apparently a preliminary picture based on crude simplifications, our representation suggests that simple drivers such as population and agriculture are useful to describe chemical pollution at European scale. From our preliminary inventory, E-PRTR industrial point emissions seem to account for a relatively small share of total emissions. Consequently, apart from specific measures such as upgrades to urban wastewater treatment plants in certain high impact areas, the management of priority substances may require a more strategic approach to emission control, addressing chemical use across sectors and the management of out-phased, legacy chemicals. At the same time, we advocate that improving emission inventories requires monitoring data reflecting the variability of emission patterns across Europe, as presently available monitoring data do not enable a catchment-specific estimation of emissions. © 2019 The Authors ; This study was partly funded by, and developed in the context of Project Globaqua within the EU Seventh Framework Programme for research, technological development and demonstration under grant agreement No 603629 . Emission factors presented in this paper were estimated by Rafael Marcé within the scope of a service contract of ICRA for the JRC (ref. 392653) funded under the Danube Water Nexus cluster of activities of the JRC in support to the EU Strategy for the Danube region. The IPChem platform is developed and maintained at the European Commission's DG JRC under the responsibility of S. Kephalopoulos. We wish to particularly thank European Commission colleagues Silvia Dalla Costa for her generous and effective support with IPChem data, and Helen Clayton for her advice on an early version of this paper. Appendix A ; Peer reviewed

Pollutants' dynamics in rivers flowing through industrial areas is linked to the entrainment and transport of contaminants attached to solid particles. The transport of sediment is mainly associated to high discharges and flood episodes, and these events constitute one of the main factors causing fluxes of buried pollutants in rivers. We performed a field study in the lower River Cinca (Ebro basin, Northeast Spain) to quantify the mobilization and transfer of several contaminants present in the river bed sediments. We focused on contaminants previously identified (PCBs, DDXs, PBDEs, HBCDs and PFRs) to occur in the river. River bed sediment samples were collected during low flows and a subsequent sampling campaign was used to capture sediment borne contaminants during a flood event. Water samples were taken at the same locations as the static sediment samples and used to determine the suspended sediment concentrations and the contaminants content (i.e. mass of contaminant per sediment mass unit) during the event. We estimated mass fluxes for both sediment and pollutants, and determined that sediment transport followed a clockwise hysteresis. This is typically observed in high flow events after dry summer periods. With sediments there was a large mobilization of PFRs (36 kg in 48 h in one of the main tributaries) and PCBs not previously observed in the static sediment. Observed contaminant load ranges during the two-day sampling campaign were: PCB (34–152 g), DDT (12–213 g), PBDE (50–1740 g), HBCD (0–2.2 g) and PFR (2410–35,895 g). An environmental risk assessment was carried out by comparing the pollutant concentrations found in the sediments with the Canadian quality guidelines (ISQC), showing a significant noncompliance for PCBs in dynamic sediments. Our results point out to the need of a regular assessment of the downstream transfer of the sediment-borne pollutants in drainage basins historically affected by intense industrial activities and associated contamination. ; The authors are grateful to the reviewers, whose valuable suggestion contributed to improving the present manuscript. This work was funded by the EU through the FP7 Project GLOBAQUA (grant agreement 603629) and the Redes de Excelencia project NET-SCARCE (CTM2015-69780-REDC). Authors acknowledge the support from the Economy and Knowledge Department of the Catalan Government through Consolidated Research Groups ICRA-ENV 2017 SGR 1124 and 2017 SGR 459 Fluvial Dynamics Research Group (RIUS). Authors thank Efren Muñoz who helped during the sampling campaign and provided turbidity data.

This book details the experiences gained by the Catalan Water Agency (ACA) in a Mediterranean watershed - the Catalan River Basin District - following the launch of the EU Water Framework Directive (WFD) in the year 2000. Groundwater and coastal water experts present 13 chapters defining tools for water-status assessment specially adapted to Mediterranean conditions. The content of this and the companion volume Experiences from Surface Water Quality Monitoring: The EU Water Framework Directive Implementation in the Catalan River Basin District (Part I) are the result of an excellent collaboration between the ACA and several Catalan universities and research centers to cope with new challenges provided by the WFD monitoring requirements. The volume serves as a useful guide for environmental managers and scientists engaged in other European as well as Non-European river basins

This book details the experiences gained by the Catalan Water Agency (ACA) in a Mediterranean watershed - the Catalan River Basin District - following the launch of the EU Water Framework Directive (WFD) in the year 2000. Experts in rivers, reservoirs, lakes, wetlands and estuaries present 13 chapters defining tools for water-status assessment specially adapted to Mediterranean conditions. The content of this and the companion volume Experiences from Ground, Coastal and Transitional Water Quality Monitoring: The EU Water Framework Directive Implementation in the Catalan River Basin District (Part II) are the result of an excellent collaboration between the ACA and several Catalan universities and research centers to cope with new challenges provided by the WFD monitoring requirements. The volume serves as a useful guide for environmental managers and scientists engaged in other European as well as Non-European river basins

Ponencia presentada en la Final RISKCYCLE conference, titulada "Risk-Based Management of Chemicals and Products in a circular economy at a global scale",celebrada en Dresden (Alemania) el 8 y 8 de mayo de 2012. ; According to the European Parliament over 1.8 billion tonnes of waste are generated each year in Europe (3.5 tonnes per person) and less than a third of it is recycled. United States produces approximately 200 million tons of garbage each year, according to the Environmental Protection Agency. ; Peer reviewed

Contamination of surface waters by pesticides continues to be the focus of concern for water authorities due to the growing evidence of their deleterious effects on aquatic life. In this context, the present work investigates the occurrence of 16 selected pesticides belonging to the classes of triazines, phenylureas, organophosphates, chloroacetanilides and thiocarbamates in surface waters from the Llobregat River (NE Spain) and some of its tributaries (Anoia and Rubí) and assesses their potential impact on the aquatic organisms by applying a recently developed index, the Short-term Pesticide Risk Index for the Surface Water System (PRISW-1), which takes into account the pesticides concentrations and their overall toxicity against three aquatic organisms (algae, Daphnia, and fish). Chemical analysis, performed by means of a fully automated method based on isotope dilution on-line solid phase extraction–liquid chromatography– electrospray–tandem mass spectrometry (on-line SPE–LC–ESI–MS/MS), revealed diuron and diazinon as the most ubiquitous and abundant compounds with levels up to 818 and 132 ng L 1, respectively. Total pesticide concentrations, which in only 1 out of 66 samples surpassed 500 ng L 1, were higher in the tributaries than in the river but their contribution in terms of mass-loads to the overall pesticide pollution of the Llobregat River was relatively small. Contamination increased downstream of the river and was clearly influenced by rainfall and hence river flow. Application of the PRISW-1 index indicated that, although pesticides levels fulfilled the European Union Environmental Quality Standards (EQS) for surface waters, the existing pesticide contamination poses a low to high ecotoxicological risk for aquatic organisms, that algae and macro-invertebrates are at higher risk than fish, and that the organophosphates diazinon and malathion and the phenylurea diuron are the major contributors to the overall toxicity and therefore the most problematic compounds. ; Peer Reviewed ; Postprint (published version)

Contamination of surface waters by pesticides continues to be the focus of concern for water authorities due to the growing evidence of their deleterious effects on aquatic life. In this context, the present work investigates the occurrence of 16 selected pesticides belonging to the classes of triazines, phenylureas, organophosphates, chloroacetanilides and thiocarbamates in surface waters from the Llobregat River (NE Spain) and some of its tributaries (Anoia and Rubí) and assesses their potential impact on the aquatic organisms by applying a recently developed index, the Short-term Pesticide Risk Index for the Surface Water System (PRISW-1), which takes into account the pesticides concentrations and their overall toxicity against three aquatic organisms (algae, Daphnia, and fish). Chemical analysis, performed by means of a fully automated method based on isotope dilution on-line solid phase extraction–liquid chromatography– electrospray–tandem mass spectrometry (on-line SPE–LC–ESI–MS/MS), revealed diuron and diazinon as the most ubiquitous and abundant compounds with levels up to 818 and 132 ng L 1, respectively. Total pesticide concentrations, which in only 1 out of 66 samples surpassed 500 ng L 1, were higher in the tributaries than in the river but their contribution in terms of mass-loads to the overall pesticide pollution of the Llobregat River was relatively small. Contamination increased downstream of the river and was clearly influenced by rainfall and hence river flow. Application of the PRISW-1 index indicated that, although pesticides levels fulfilled the European Union Environmental Quality Standards (EQS) for surface waters, the existing pesticide contamination poses a low to high ecotoxicological risk for aquatic organisms, that algae and macro-invertebrates are at higher risk than fish, and that the organophosphates diazinon and malathion and the phenylurea diuron are the major contributors to the overall toxicity and therefore the most problematic compounds. ; Peer Reviewed ; Postprint (published version)