Suchergebnisse

The origin of different stability of crystalline calcium silicate hydrates was investigated. The tobermorite crystal has been used as an analog of cement hydrate that is being mostly manufactured material on earth. Normal tobermorite is thermally unstable and transforms to amorphous at low pressure. Meanwhile, anomalous tobermorite with high Al content does not significantly transform under high pressure or high temperature. Conducted X-ray absorption spectroscopy explains the weak stability of normal tobermorite which was originally hypothesized by the role of zeolitic Ca ions in the cavities of silicate chains. Atomic simulations reproduced the experimentally observed trend of pressure behavior once the ideal structures were modified to account for the Al content as well as the chain defects. The simulations also suggested that the stability of tobermorite under stress could be rationalized as a self-healing mechanism in which the structural instabilities were accommodated by a global sliding of the CaO layer. ; J.M. acknowledges support by a grant (20SCIP-C159063-01) from Construction Technology Research Program funded by Ministry of Land, Infrastructure and Transport of Korean government. H.M. acknowledges the financial support from the Gobierno Vasco (project IT912-16). The work in San Sebastián (R.D., J.S.D, A.A) was supported by the Spanish Ministry of Science and Innovation with RTI2018-098554-B-I00, PID2019-105488GB-I00 and PCI2019-103657 research grants, the Gobierno Vasco UPV/EHU (Project No. IT-1246-19), and the European Commission from the NRG-STORAGE project (GA 870114). The Institute of Engineering Research in Seoul National University provided research facilities for this work. The Ca-XAS and HPXRD experiments were performed at XAFCA beamline in Singapore Synchrotron Light Source (SSLS) and 12.2.2 beamline in Advanced Light Source (ALS), respectively. The ALS supported by a DOE Office of Science User Facility under contract no. DE-AC02-05CH11231 and the Consortium for Materials Properties Research in Earth Sciences under NSF Cooperative Agreement EAR 1606856. ; Peer reviewed

In 2016, an average of 5.0 tons of waste per household was generated in the European Union (including waste glass). In the same year, 45.7% of the waste glass in the EU was recycled. The incorporation of recycled waste glass in building materials, i.e., concrete, cements, or ceramics, is very popular around the world because of the environmental problems and costs connected with their disposal and recycling. A less known solution, however, is using the waste glass in composite products, including sand-lime. The aim of this work was to assess the role of recycled container waste glass in a sand-lime mix. The waste was used as a substitute for the quartz sand. To verify the suitability of recycled glass for the production of sand-lime products, the physical and mechanical properties of sand-lime specimens were examined. Four series of specimens were made: 0%, 33%, 66%, and 100% of recycled waste glass (RG) as a sand (FA) replacement. The binder mass did not change (8%). The research results showed that ternary mixtures of lime, sand, and recycled waste glass had a higher compressive strength and lower density compared to the reference specimen. The sand-lime specimen containing 100% (RG) increased the compressive strength by 287% compared to that of the control specimen. The increase in the parameters was proportional to the amount of the replacement in the mixtures.

The construction industry in a special way affects the condition of the state of the environment
and human. It is necessary to search for materials with the lowest degree of risk to humans. The aim
of the article is to focus attention on the materials which are composed of natural components such
as: SiO2, CaO, H2O, and next on the thermal and moisture management of the material in the aspect
of development of harmful microorganisms in construction materials (including the modified ones).
The microstructure of the materials usually includes tobermorite with a ratio CaO/SiO2 = 0.83
and C-S-H phase, impregnability 16%, and compressive strength minimum 13 MPa. The article
proposes the use of the ASR (Additive Ratio Assessment-ARAS) method to develop a model and analysis
of the used building materials that affect the microclimate in the room. A case study can be defined
as a decision problem.
Keywords: architecture, sand, lime, silicate, environment, protection, recycling, ARAS.

Abstract
Red mud (RM) cementitious materials were prepared with the thermally, thermoalkali- or thermocalcium-activated RM, steel slag (SS), and other additives. The effects of different thermal RM activation methods on the cementitious material hydration mechanisms, mechanical properties, and environmental risks were discussed and analyzed. The results showed that the hydration products of different thermally activated RM samples were similar with the main products being C-S–H, tobermorite, and Ca(OH)2. Ca(OH)2 was mainly present in thermally activated RM samples, and the tobermorite was mainly produced by samples prepared with thermoalkali- and the thermocalcium-activated RM. The mechanical properties of the samples prepared by thermally and thermocalcium-activated RM had early-strength properties, while the thermoalkali-activated RM samples were similar to the late-strength type of cement properties. The average flexural strength of thermally and the thermocalcium-activated RM samples at 14 days were 3.75 MPa and 3.87 MPa respectively, whereas, the 1000 °C thermoalkali-activated RM samples only at 28 days was 3.26 MPa; the above data could reach the single flexural strength (3.0 MPa) of the first-grade pavement blocks of the building materials industry standard of the People's Republic of China-concrete pavement blocks (JC/T446-2000). The optimal preactivated temperature for different thermally activated RM was different; the optimal preactivated temperature for both thermally and thermocalcium-activated RM was 900 °C, and the flexural strength was 4.46 MPa and 4.35 MPa, respectively. However, the optimal preactivated temperature of thermoalkali activated RM at 1000 °C. The 900 °C thermally activated RM samples had better solidified effects for heavy metal elements and alkali substances. 600~800℃ thermoalkali activated RM samples had better solidified effects for heavy metal elements. Different temperatures of thermocalcium-activated RM samples showed different solidified effects on different heavy metal elements, which may be due to the influence of thermocalcium activation temperature on the structural changes of the hydration products of the cementitious samples. In this study, three thermal RM activation methods were proposed, and the co-hydration mechanism and environmental risk study of different thermally activated RM and SS were further elucidated. This not only provides an effective method for the pretreatment and safe utilization of RM, but also facilitates the synergistic resource treatment of solid waste and further promotes the research process of replacing part of traditional cement with solid waste.

AbstractRed mud (RM) is a solid waste material with high alkalinity and low cementing activity component. The low activity of RM makes it difficult to prepare high-performance cementitious materials from RM alone. Five groups of RM-based cementitious samples were prepared by adding steel slag (SS), grade 42.5 ordinary Portland cement (OPC), blast furnace slag cement (BFSC), flue gas desulfurization gypsum (FGDG), and fly ash (FA). The effects of different solid waste additives on the hydration mechanisms, mechanical properties, and environmental safety of RM-based cementitious materials were discussed and analyzed. The results showed that the samples prepared from different solid waste materials and RM formed similar hydration products, and the main products were C–S–H, tobermorite, and Ca(OH)2. The mechanical properties of the samples met the single flexural strength criterion (≥ 3.0 MPa) for first-grade pavement brick in the Industry Standard of Building Materials of the People's Republic of China-Concrete Pavement Brick. The alkali substances in the samples existed stably, and the leaching concentrations of the heavy metals reached class III of the surface water environmental quality standards. The radioactivity level was in the unrestricted range for main building materials and decorative materials. The results manifest that RM-based cementitious materials have the characteristics of environmentally friendly materials and possess the potential to partially or fully replace traditional cement in the development of engineering and construction applications and it provides innovative guidance for combined utilization of multi-solid waste materials and RM resources.