Suchergebnisse

This work has been supported by the University of Oviedo, under Project PAPI-17-PEMERG-9, and by the Spanish Government, under Project MINECO: CTQ2017-86994-R.

Rapid and sensitive detection of chemical and biological analytes becomes increasingly important in areas such as medical diagnostics, food control and environmental monitoring. Optical biosensors based on surface plasmon resonance (SPR) and optical waveguide spectroscopy have been extensively pushed forward in these fields. In this study, we combine SPR, surface plasmon-enhanced fluorescence spectroscopy (SPFS) and optical waveguide spectroscopy with hydrogel thin film for highly sensitive detection of molecular analytes.rnrnA novel biosensor based on SPFS which was advanced through the excitation of long range surface plasmons (LRSPs) is reported in this study. LRSPs are special surface plasmon waves propagating along thin metal films with orders of magnitude higher electromagnetic field intensity and lower damping than conventional SPs. Therefore, their excitation on the sensor surface provides further increased fluorescence signal. An inhibition immunoassay based on LRSP-enhanced fluorescence spectroscopy (LRSP-FS) was developed for the detection of aflatoxin M1 (AFM1) in milk. The biosensor allowed for the detection of AFM1 in milk at concentrations as low as 0.6 pg mL-1, which is about two orders of magnitude lower than the maximum AFM1 residue level in milk stipulated by the European Commission legislation.rnrnIn addition, LRSPs probe the medium adjacent to the metallic surface with more extended evanescent field than regular SPs. Therefore, three-dimensional binding matrices with up to micrometer thickness have been proposed for the immobilization of biomolecular recognition elements with large surface density that allows to exploit the whole evanescent field of LRSP. A photocrosslinkable carboxymethyl dextran (PCDM) hydrogel thin film is used as a binding matrix, and it is applied for the detection of free prostate specific antigen (f-PSA) based on the LRSP-FS and sandwich immunoassay. We show that this approach allows for the detection of f-PSA at low femto-molar range, which is approximately four orders of magnitude lower than that for direct detection of f-PSA based on the monitoring of binding-induced refractive index changes.rnrnHowever, a three dimensional hydrogel binding matrix with micrometer thickness can also serve as an optical waveguide. Based on the measurement of binding-induced refractive index changes, a hydrogel optical waveguide spectroscopy (HOWS) is reported for a label-free biosensor. This biosensor is implemented by using a SPR optical setup in which a carboxylated poly(N-isoproprylacrylamide) (PNIPAAm) hydrogel film is attached on a metallic surface and modified by protein catcher molecules. Compared to regular SPR biosensor with thiol self-assembled monolayer (SAM), HOWS provides an order of magnitude improved resolution in the refractive index measurements and enlarged binding capacity owing to its low damping and large swelling ratio, respectively. A model immunoassay experiment revealed that HOWS allowed detection of IgG molecules with a 10 pM limit of detection (LOD) that was five-fold lower than that achieved for SPR with thiol SAM. For the high capacity hydrogel matrix, the affinity binding was mass transport limited.rnrnThe mass transport of target molecules to the sensor surface can play as critical a role as the chemical reaction itself. In order to overcome the diffusion-limited mass transfer, magnetic iron oxide nanoparticles were employed. The magnetic nanoparticles (MNPs) can serve both as labels providing enhancement of the refractive index changes, and "vehicles" for rapidly delivering the analytes from sample solution to an SPR sensor surface with a gradient magnetic field. A model sandwich assay for the detection of β human chorionic gonadotropin (βhCG) has been utilized on a gold sensor surface with metallic diffraction grating structure supporting the excitation of SPs. Various detection formats including a) direct detection, b) sandwich assay, c) MNPs immunoassay without and d) with applied magnetic field were compared. The results show that the highly-sensitive MNPs immunoassay improves the LOD on the detection of βhCG by a factor of 5 orders of magnitude with respect to the direct detection.rn ; 132 S.

M.A. Butt, M.C. Pujol, R. Solé, A. Ródenas, G. Lifante, M. Aguiló, F. Díaz, S. N. Khonina, R. V. Skidanov and Payal Verma, "Fabrication of optical waveguides in RbTiOPO4 single crystals by using different techniques", XIII International Scientific and Technical Conference on Optical Technologies in Telecommunications,SPIE 9807 (26 March, 2016): doi:10.1117/12.2231368. One print or electronic copy may be made for personal use only. Systematic reproduction and distribution, duplication of any material in this paper for a fee or for commercial purposes, or modification of the content of the paper are prohibited ; Proceedings of XIII International Scientific and Technical Conference on Optical Technologies in Telecommunications Conference (Ufa, Russian Federation) ; In this work, we have demonstrated the use of different technologies to fabricate straight channel waveguides, S-bend waveguides, Y-splitter and Mach -Zehnder (MZ) structures on RbTiOPO 4 crystals and its isomorphs. We used reactive ion etching (RIE), inductively coupled plasma-RIE (ICP-RIE), femtosecond pulse laser micro-fabrication and ion diffusion techniques to structure these crystals. Computer simulations have been carried out and compared with the optical characterization of the waveguides which are in agreement with each other. ; This work is supported by the Ministry of Education and Science of the Russian Federation, Russian Science Foundation (grant No. 14-19-00114), Spanish Government under Projects MAT2011-29255-C02-02, TEC2014-55948-R, MAT2013-47395, C4-4-R/1-R and by the Catalan Authority under Project 2014SGR1358

In this work, high-quality FASnI3 (FA, formamidinium) lead-free perovskite thin films are successfully incorporated in a flexible polyethylene terephthalate (PET) substrate to demonstrate amplified spontaneous emission (ASE) and lasing. The waveguide (WG) consists of polymethylmethacrylate(PMMA)/FASnI3 bilayer deposited on a PET substrate and is properly designed to allow single-mode propagation at the photoluminescence wavelength. This geometry optimizes the excitation of the emitting FASnI3, enhances the light−matter interaction in the semiconductor thin film, provides a preferable direction for the emitted light and allows its direct outcoupling for on-chip or fiber-optic applications. As far as the authors know, ASE and random lasing are obtained for the first time in a flexible-based WG integrating a highly efficient lead-free perovskite. The high quality of the deposited films and the optimized design of the structure result in an extremely low ASE/lasing threshold in the range of 1 µJ cm−2, which is only ten times higher than that measured in the same PMMA/FASnI3 structure deposited on a rigid substrate (Si/SiO2). More interestingly, these WGs exhibit a strong polarization anisotropy for the outcoupled ASE/lasing light with a preferable transverse electric polarization. This work is the base for the future development of ecofriendly, flexible, and efficient photonic devices. ; This project received funding from the European Union's Horizon 2020 research and innovation programme under grant agreement No 862656 (project DROP-IT) and the European Research Council (ERC) via Consolidator Grant (724424, No-LIMIT) and by the Spanish MINECO through projects no. PID2020-120484RB-I00 and PID2019-107314RB-I00 (Stable).

According to recent market studies of the North American company Allied Market Research, the field of photonic sensors is an emerging strategic field for the following years and it is expected to garner $18 billion by 2021. The integration of micro and nanofabrication technologies in the field of sensors has allowed the development of new technological concepts such as lab-on-a-chip, which have achieved extraordinary advances in terms of detection and applicability, for example in the field of biosensors. This continuous development has allowed that equipment consisting of many complex devices that occupied a whole room a few years ago, at present it is possible to handle them in the palm of the hand; that formerly long duration processes are carried out in a matter of milliseconds and that a technology previously dedicated solely to military or scientific uses is available to the vast majority of consumers. The adequate combination of micro and nanostructured coatings with optical fiber sensors has permitted us to develop novel sensing technologies, such as the first experimental demonstration of lossy mode resonances (LMRs) for sensing applications, with more than one hundred citations and related publications in high rank journals and top conferences. In fact, fiber optic LMR-based devices have been proven as devices with one of the highest sensitivity for refractometric applications. Refractive index sensitivity is an indirect and simple indicator of how sensitive the device is to chemical and biological species, topic where this proposal is focused. Consequently, the utilization of these devices for chemical and biosensing applications is a clear opportunity that could open novel and interesting research lines and applications as well as simplify current analytical methodologies. As a result, on the basis of our previous experience with LMR based sensors to attain very high sensitivities, the objective of this paper is presenting the route for the development of label-free optical waveguide sensing platform ...

According to recent market studies of the North American company Allied Market Research, the field of photonic sensors is an emerging strategic field for the following years and it is expected to garner $18 billion by 2021. The integration of micro and nanofabrication technologies in the field of sensors has allowed the development of new technological concepts such as lab-on-a-chip which have achieved extraordinary advances in terms of detection and applicability, for example in the field of biosensors. This continuous development has allowed that equipment consisting of many complex devices that occupied a whole room a few years ago, at present it is possible to handle them in the palm of the hand; that formerly long duration processes are carried out in a matter of milliseconds and that a technology previously dedicated solely to military or scientific uses is available to the vast majority of consumers. The adequate combination of micro and nanostructured coatings with optical fiber sensors has permitted us to develop novel sensing technologies, such as the first experimental demonstration of lossy mode resonances (LMRs) for sensing applications, with more than one hundred citations and related publications in high rank journals and top conferences. In fact, fiber optic LMR-based devices have been proven as devices with one of the highest sensitivity for refractometric applications. Refractive index sensitivity is an indirect and simple indicator of how sensitive the device is to chemical and biological species, topic where this proposal is focused. Consequently, the utilization of these devices for chemical and biosensing applications is a clear opportunity that could open novel and interesting research lines and applications as well as simplify current analytical methodologies. As a result, on the basis of our previous experience with LMR based sensors to attain very high sensitivities, the objective of this paper is presenting the route for the development of label-free optical waveguide sensing platform based on LMRs that enable to explore the limits of this technology for bio-chemosensing applications. ; This work was supported in part by the Spanish Ministry of Education and Science-FEDER TEC2016- 78047-R, Government of Navarra 0011-1365-2017- 000117 and Public University of Navarra PJUPNA26 research grants as well as the ATTRACT call financed by the European Union's Horizon 2020 research and innovation programme under grant agreement No. 777222.

We report on the direct low-repetition rate femtosecond pulse laser microfabrication of optical waveguides in KTP crystals and the characterization of refractive index changes after the thermal annealing of the sample, with the focus on studying the potential for direct laser fabricating Mach-Zehnder optical modulators. We have fabricated square cladding waveguides by means of stacking damage tracks, and found that the refractive index decrease is large for vertically polarized light (c-axis; TM polarized) but rather weak for horizontally polarized light (a-axis; TE polarized), this leading to good near-infrared light confinement for TM modes but poor for TE modes. However, after performing a sample thermal annealing we have found that the thermal process enables a refractive index increment of around 1.5x10−3 for TE polarized light, while maintaining the negative index change of around −1x10−2 for TM polarized light. In order to evaluate the local refractive index changes we have followed a multistep procedure: We have first characterized the waveguide cross-sections by means of Raman micro-mapping to access the lattice micro-modifications and their spatial extent. Secondly we have modeled the waveguides following the modified region sizes obtained by micro-Raman with finite element method software to obtain a best match between the experimental propagation modes and the simulated ones. Furthermore we also report the fabrication of Mach-Zehnder structures and the evaluation of propagation losses. ; This work was partially supported by the Ministerio de Economía y Competitividad, under Project FIS2013-44174-P, by the Spanish Government under project MAT2013-47395-C4-4-R and TEC2014-55948-R and by the Generalitat de Catalunya under project 2014SGR1358. F.D. acknowledges additional support through the ICREA academia award 2010ICREA-02 for excellence in research.

In this review our recent results on the electron-beam domain writing (EBDW) on the nonpolar surfaces of LiNbO3 crystals of different compositions are presented. The obtained results permitted us to relate the main characteristics of domain formation (the domain sizes and velocity Vf of the frontal motion) to the irradiation conditions (the accelerating voltage U of scanning electron microscopy, EB-current I, the inserted charge Q). The domain depth Td is controlled by U via the electron penetration depth; the domain length Ld increases linearly with Q owing to the domain frontal growth by the viscous friction law. In optical waveguides, the matching of the Td value with the waveguide thickness D provides optimal values of the waveguide conversion to the second harmonic

[EN] Switches are essential components in several optical applications, in which reduced footprints are highly desirable for mass production of densely integrated circuits at low cost. However, most conventional solutions rely on making long switching structures, thus increasing the final device size. Here, we propose and experimentally demonstrate an ultra-compact 2x2 optical switch based on slow-light-enhanced bimodal interferometry in one-dimensional silicon photonic crystals. By properly designing the band structure, the device exhibits a large group index contrast between the fundamental even mode and a higher order odd mode for TE polarization. Thereby, highly dispersive and broadband bimodal regions for high-performance operation are engineered by exploiting the different symmetry of the modes. Two configurations are considered in the experiments to analyze the dimensions influence on the switching efficiency. As a result, a photonic switch based on a bimodal single-channel interferometer with a footprint of only 63 mu m(2), a power consumption of 19.5 mW and a crosstalk of 15 dB is demonstrated for thermo-optic tunability. ; This work was supported in part by Generalitat Valenciana under Grants AVANTI/2019/123 and ACIF/2019/009, in part by the Spanish Ministerio de Ciencia e Innovacion through PID2019-106965RBC21 and PID2019-111460GB-I00 projects, and in part by the European Union through the operational program of the European Regional Development Fund (FEDER) of the Valencia Regional Government 2014-2020 ; Torrijos-Morán, L.; Brimont, ACJ.; Griol Barres, A.; Sanchis Kilders, P.; García-Rupérez, J. (2021). Ultra-compact optical switches using slow light bimodal silicon waveguides. Journal of Lightwave Technology. 39(11):3495-3501. https://doi.org/10.1109/JLT.2021.3066479 ; S ; 3495 ; 3501 ; 39 ; 11

Low cost counting of cells has medical applications in screening, military medicine, disaster medicine, and rural healthcare. In this report, we present a shallow, buried, planar waveguide fabricated by potassium ion exchange in glass that enables low-cost and rapid counting of metal-tagged objects that lie in the evanescent field of the waveguide. Laser light transmitted through the waveguide was attenuated proportionately to the presence of metal-coated microstructures fabricated from photoresist. This technology enables the low-cost enumeration of cells from blood, urine, or other biofluids.

We report on waveguide lasers at 1064.5 nm in femtosecond laser-written double-cladding waveguides in Nd∶GdVO4 crystals. The cladding waveguides guide both transverse electric (TE)- and transverse magnetic (TM)-polarized modes with considerably symmetric single-modal profiles and show good transmission properties (propagation loss as low as 1.0 dB∕cm). The detailed structure of the single and double claddings has been imaged by means of μ-Raman analysis, and the observed slight fabrication asymmetries with respect to an ideal circular cladding are in well agreement with the observed differences in TE/TM propagation losses. Importantly, the Raman imaging shows the complete absence of lattice defect at the laser active volume. Under the optical pumping at 808 nm, a maximum output power up to 0.43Wof the continuous wave waveguide laser with a slope efficiency of 52.3% has been achieved in the double-cladding waveguide, which is 21.6% and 23% higher than that from a single-inner cladding waveguide. Furthermore, the maximum output power of the waveguide laser is 72% higher than that of the double-line waveguide due to the double-cladding design ; The work is supported by the National Natural Science Foundation of China (No. 11274203), the Specialized Research Fund for the Doctoral Program of Higher Education of China (No. 20130131130001), and Junta de Castilla y León under project SA086A12-2. Support from the Centro de Láseres Pulsados (CLPU) is also acknowledged. This work was supported by the Spanish Government under project MAT2011- 29255-C02-02 and by the Generalitat de Catalunya under project 2014SGR1358.

In this work the fabrication of buried optical waveguides by femtosecond laser inscription in the 0.8CaSiO3–0.2Ca3(PO4)2 eutectic glass doped with Nd3+ ions is reported. The glass samples were prepared by melting the eutectic powder mixture in a Pt–10 wt.% Rh crucible at 1600 °C and pouring it in a preheated brass mould. Afterwards, the glass was annealed to release the inner stresses. Buried waveguides were fabricated by focusing beneath the surface a pulsed Ti:sapphire laser with a pulsewidth of 120 fs working at 1 kHz. Two adjacent parallel tracks were written to define a region where an increase in the refractive index occurs. The effects produced by the variation of the laser pulse energy as well as the lateral separation between tracks, scanning speed and focusing distance were studied. After the laser processing, the near-field intensity distribution at 633 nm of the waveguide's modes was studied demonstrating the confinement of both, the TE as the TM polarizations. In order to diminish the losses induced by colour centres absorption, heat treatments were carried out in the samples. The waveguide's modes were compared with respect to the samples without heat treatments. The spectroscopic properties of the neodymium ions have been characterized to evaluate in what extent their optical properties could be modified by the waveguide fabrication process and to elucidate the potential application of such waveguides as integrated laser sources. ; This work was supported by the Spanish Government MEC under Projects No. MAT2009-14282-C02-02, MAT2010-17753, FIS2011-27968, FIS2009-09522, Consolider SAUUL CSD2007-00013, Basque Country Government (IT-331-07) and TEC2010-21574-C02-01. Daniel Sola thanks the JAE-DOC program and the Science and Technology Inter-Ministry commission of Spain and FEDER funds of the EC under project MAT2009-13979-C03-03 for the financial support of his contract.

4 págs,; 5 figs. ; Ridge waveguide lasers have been fabricated on Nd doped LiNbO crystals. The fs-laser writing technique was used to define ridge structures on a gradient-index planar waveguide fabricated by Zn-diffusion. This planar waveguide was formed in a z-cut LiNbO substrate homogeneously doped with a 0.23% of Nd ions. To obtain lateral light confinement, the surface was then micromachined using a multiplexed femtosecond laser writing beam, forming the ridge structures. By butting two mirrors at the channel waveguide end-facets, forming a waveguide laser cavity, TM-polarized laser action at 1085 nm was achieved by end-fire TM-pumping at 815 nm. The waveguide laser shows a threshold of 31 mW, with a 7% of slope efficiency. © 2016 Elsevier B.V. All rights reserved ; This work was supported by the Spanish Government under projects TEC2014-52642-C2-1-R and MAT2013-47395-C4. ; Peer Reviewed

This work was supported by ERDF 1.1.1.1 Activity Project Nr. 1.1.1.1/16/A/046 "Application assessment of novel organic materials by prototyping of photonic devices". We acknowledge Igors MIHAILOVS for valuable discussions. ; An all-organic Mach-Zehnder waveguide device for volatile solvent sensing is presented. Optical waveguide devices offer a great potential for various applications in sensing and communications due to multiple advantageous properties such as immunity to electromagnetic interference, high efficiency, and low cost and size. One of the most promising areas for applications of photonic systems would be real-time monitoring of various hazardous organic vapor concentrations harmful to human being. The optical waveguide volatile solvent sensor presented here comprises a novel organic material applied as a cladding on an SU-8 waveguide core and can be used for sensing of different vapors such as isopropanol, acetone, and water. It is shown that the reason for the chemical sensing in device is the absorption of vapor into the waveguide cladding which in turn changes the waveguide effective refractive index. The presented waveguide device has small footprint and high sensitivity of the mentioned solvent vapor, particularly that of water. The preparation steps of the device as well as the sensing characteristics are presented and discussed. ; ERDF 1.1.1.1 Activity Project Nr. 1.1.1.1/16/A/046; Institute of Solid State Physics, University of Latvia as the Center of Excellence has received funding from the European Union's Horizon 2020 Framework Programme H2020-WIDESPREAD-01-2016-2017-TeamingPhase2 under grant agreement No. 739508, project CAMART² ; https://link.springer.com/article/10.1007%2Fs13320-019-0543-z

The laser performance and crystalline micro-structural properties of near-infrared step-index channel waveguides fabricated inside Neodymium doped YAG laser ceramics by means of three-dimensional sub-picosecond pulse laser direct writing are reported. Fluorescence micro-mapping of the waveguide cross-sections reveals that an essential crystal lattice re-distribution has been induced after short pulse irradiation. Such lattice re-distribution is evidenced at the waveguide core corresponding to the laser written refractive index increased volume. The waveguides core surroundings also present diverse changes including slight lattice disorder and bi-axial strain fields. The step-index waveguide laser performance is compared with previous laser fabricated waveguides with a stress-optic guiding mechanism in absence of laser induced lattice re-distribution ; This work was supported by the Spanish Government under Project Nos. MAT2013-47395-C4-1-R, TEC2010- 21574-C02-01/02, MAT2013-47395-C4, and MAT2011- 29255-C02-02 and by the Generalitat de Catalunya under Project No. 2014SGR1358. A. Benayas thanks Fonds de recherche du Quebec-Nature et technologies (FRQNT) for the Postdoctoral Fellowship given to him through Programme de Bourses d'Excellence (Merit Scholarship Program for Foreign Students).