Suchergebnisse

This completely revised and updated fourth edition of the best-selling classic is a thorough treatment of the subject while remaining concise and readable. New additions include capillary electrophoresis, monolithic columns, zwitterion colums, DNA/RNA analysis, fundamentals of the science of IC, and micro methods. The whole is rounded off by handy tables with details on detection or elution conditions, among others.

AbstractPrevious attempts to utilize ion chromatography for the analysis of sea water samples have failed through chronic interference by the major ions (na, Mg, Ca) during the preconcentration stage. As part of ongoing research into ion chromatography, a technique has been developed to overcome these interferences, using a two‐stage preconcentration step, prior to separation on a cation‐exchange column. This has made it possible to detect μg/l quantities of trace metals in samples containing g/l concentrations of sodium, magnesium and calcium. A modified commercially‐available ion chromatographic system was used to analyse copper, nickel, zinc, cobalt and manganese in saline waters. Detection limits were typically less than 1 μg/l, with relative standard deviation of less than 10%. Hence this new method has the potential to provide an inexpensive multi‐elemental sea water analysis with the minimum of handling. In addition, the simplicity and sensitivity of the technique may make it suitable for unattended use as a remote monitor of metals.

A direct ion chromatographic method for the determination of chlorite, chlorate, and bromate in the presence of fluoride, chloride, nitrate, nitrite, and bromide in treated drinking waters was described. Separation of target analytes was achieved using an AS19-HC analytical column (250 mm x 4 mm), AG 19- HC guard column (50 mm x 4 mm), and KOH 25 mmol/L as mobile phase. Inorganic analytes were eluted using a flow rate of 1 mL/min. The column temperature was set up and maintained at 300C. The analyte ions
were quantified using a suppressed conductivity detector.

This paper presents information about the usefulness of a high-performance anion exchange chromatography HPAEC-PED method for determination of the mannitol content in beet processing samples. The method can also determine glucose, fructose, sucrose and raffinose in the same run. Interference by formalin has been overcome.

AbstractQuantification of per‐ and polyfluoroalkyl substances (PFAS) via mass spectrometry is highly sensitive but targets a limited number of compounds and the instrumentation is not available in many laboratories. We developed a methodology to determine total organofluorine by modifying a total organic carbon analyzer, which is common in laboratories across disciplines. Evolved hydrogen fluoride was captured in an impinger and analyzed by ion chromatography. Recovery of fluorine from 20 PFAS was dependent on terminal functional group and alkyl chain length. The method detection limit based on perfluorooctanoic acid (PFOA) spiked samples was 36 μg‐F/L (52 μg PFOA/L). Fluorine recoveries of spiked PFAS in river water and wastewater were similar to those spiked in deionized water. The recovery of inorganic fluorine present in sodium fluoride was 91%. Therefore, researchers should be cautious when applying methods that pre‐combust samples to differentiate organo‐ and inorganic fluorine, because the combustion process may cause inadvertent losses of inorganic fluorine, resulting in an overestimation of organofluorine.Article Impact StatementResults enable the quantification of per‐ and polyfluoroalkyl substances using equipment present in a greater number of laboratories than mass spectrometry‐based methods.