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Graphene functionalization with organics is expected to be an important step for the development of graphene-based materials with tailored electronic properties. However, its high chemical inertness makes difficult a controlled and selective covalent functionalization, and most of the works performed up to the date report electrostatic molecular adsorption or unruly functionalization. We show hereafter a mechanism for promoting highly specific covalent bonding of any amino-terminated molecule and a description of the operating processes. We show, by different experimental techniques and theoretical methods, that the excess of charge at carbon dangling-bonds formed on single-atomic vacancies at the graphene surface induces enhanced reactivity towards a selective oxidation of the amino group and subsequent integration of the nitrogen within the graphene network. Remarkably, functionalized surfaces retain the electronic properties of pristine graphene. This study opens the door for development of graphene-based interfaces, as nano-bio-hybrid composites, fabrication of dielectrics, plasmonics or spintronics. ; The research leading to these results has received funding from the Spanish MINECO (through Grants No. MAT2014-54231-C4-1-P, MAT2016-80394-R, RYC-2014-16626 and RYC-2015-17730), from the EU via the ERC-Synergy Program (Grant No. ERC-2013-SYG-610256 Nanocosmos) and the European Union Seventh Framework Program (Grant No. 604391 Graphene Flagship), and from the Comunidad Autónoma de Madrid (CAM) via the MAD2D-CM Program (Grant No. S2013/MIT-3007). We also thank the computing resources from CTI-CSIC. R.L. acknowledges financial support from Spanish MINECO under Grant agreement No. CONSOLIDER INGENIO CSD2009-00013. ; Peer reviewed

7 páginas, 4 figuras, 1 esquema.-- PACS numbers 73.20.Mf, 78.30.cd, 82.33.Hk. ; We report the synthesis, characterization and modellization of optical anion sensors based on gold nanoparticles (Au NPs) stabilized by amino-functional imidazolium ionic liquids (AFIL). The addition of different salts results in anion exchange of the imidazolium ionic liquid stabilizer leading to a change in the optical response of the original nanoparticle aqueous solution. In all cases except with dodecylbenzenesulfonic acid sodium salt, a sufficient amount of salt concentration (5 times larger than equimolar) leads to the appearance of an absorption band between 600 and 700 nm in the ultravioletvisible (UV-vis) spectrum. The presence of the salt produces aggregation of the particles that localise the optical response and produce a large spectral red shift. Transmission electron microscopy images demonstrated that this optical change was due to the aggregation of the nanoparticles. We simulate the optical response of both situations, before and after salt addition, and interpret the experimental observations in terms of the different response of metallic single nanoparticles and nanoparticle aggregates. Theoretical calculations for single nanoparticle and single nanoparticle dimers demonstrate that the colour change is not due to the enlargement or structural changes of the Au NPs, but due to the formation of NP aggregation. These results show the potential of nanoparticle plasmonics to perform effective chemical sensing. ; The authors acknowledge financial supports from the Department of Industry of the Government of the Basque Country (Eusko Jaurlaritza) and the Department of innovation of the Diputación Foral de Gipuzkoa through the ETORTEK project NANOTRON and inanoGUNE. ; Peer reviewed

AbstractOver the past several years, atomically thin two‐dimensional carbides, nitrides, and carbonitrides, otherwise known as MXenes, have been expanded into over fifty material candidates that are experimentally produced, and over one hundred fifty more candidates that have been theoretically predicted. They have demonstrated transformative properties such as metallic‐type electrical conductivities, optical properties such as plasmonics and optical nonlinearity, and key surface properties such as hydrophilicity, and unique surface chemistry. In terms of their applications, they are poised to transform technological areas such as energy storage, electromagnetic shielding, electronics, photonics, optoelectronics, sensing, and bioelectronics. One of the most promising aspects of MXene's future application in all the above areas of interest, we believe, is reliably developing their flexible and bendable electronics and optoelectronics by printing methods (henceforth, termed as printed flexible MXetronics). Designing and manipulating MXene conductive inks according to the application requirements will therefore be a transformative goal for future printed flexible MXetronics. MXene's combined property of high electrical conductivity and water‐friendly nature to easily disperse its micro/nano‐flakes in an aqueous medium without any binder paves the way for designing additive‐free highly conductive MXene ink. However, the chemical and/or structural and hence functional stability of water based MXene inks over time is not reliable, opening research avenues for further development of stable and conductive MXene inks. Such priorities will enable applications requiring high‐resolution and highly reliable printed MXene electronics using state‐of‐the art printing methods. Engineering MXene structural and surface functional properties while tuning MXene ink rheology in benign solvents of choice will be a key for ink developments. This review article summarizes the present status and prospects of MXene inks and their use in inkjet‐printed (IJP) technology for future flexible and bendable MXetronics.

We present experimental and theoretical results of the molecular sensing performance of a novel platform based on magnetic modulation of surface-enhanced infrared absorption spectroscopy. For this, we study the effect that molecular infrared vibrations of a PMMA layer have on the optical and magneto-refractive response of spintronic antennas. Specifically, a periodic array of rods is fabricated from giant-magneto-resistance Au/Ni81Fe19 metallic multilayers, and the effect of depositing a layer of PMMA on top of the array is investigated from both experimental and theoretical points of view. We find that the relative changes induced by the infrared vibrations of PMMA on the magneto-refractive signal are larger than the relative changes induced on the optical transmission. This result indicates that the magneto-refractive response is more sensitive to the excitation of molecular vibrations than the optical response and fosters the development of a novel type of an infrared sensing technique based on spintronic antennas: Magneto-Refractive Surface-Enhanced Infrared Absorption (SEIRA) Spectroscopy. ; We acknowledge financial support from MINECO through projects AMES (No. MAT 2014-58860-P), Quantum Spin Plasmonics (No. FIS2015-72035-EXP), and MIRRAS (No. MAT2017-84009-R) and Comunidad de Madrid (CM) through project SINOXPHOS-CM (No. S2018/BAA-4403). We acknowledge the service from the MiNa Laboratory at IMN and funding from MINECO under Project No. CSIC13-4E-1794 and from CM under Project No. S2013/ICE-2822 (Space-Tec), both with support from EU (FEDER, FSE). L.B., N.Z., and J.A. acknowledge support from the Department of Education, Research and Universities of the Basque Government through Project Ref. No. IT-1164-19, the Department of Industry of the Basque Government through Project No. KK-2018/00001, and the Spanish MICIN through Project Ref. No. PID2019-107432GB-I00. ; Peer reviewed

Electromagnetic field localization in nanoantennas is one of the leitmotivs that drives the development of plasmonics. The near-fields in these plasmonic nanoantennas are commonly addressed theoretically within classical frameworks that neglect atomic-scale features. This approach is often appropriate since the irregularities produced at the atomic scale are typically hidden in far-field optical spectroscopies. However, a variety of physical and chemical processes rely on the fine distribution of the local fields at this ultraconfined scale. We use time-dependent density functional theory and perform atomistic quantum mechanical calculations of the optical response of plasmonic nanoparticles, and their dimers, characterized by the presence of crystallographic planes, facets, vertices, and steps. Using sodium clusters as an example, we show that the atomistic details of the nanoparticles morphologies determine the presence of subnanometric near-field hot spots that are further enhanced by the action of the underlying nanometric plasmonic fields. This situation is analogue to a self-similar nanoantenna cascade effect, scaled down to atomic dimensions, and it provides new insights into the limits of field enhancement and confinement, with important implications in the optical resolution of field-enhanced spectroscopies and microscopies. ; We acknowledge financial support from projects FIS2013-14481-P and MAT2013-46593-C6-2-P from MINECO. M.B., P.K., F.M., and D.S.P. also acknowledge support from the ANR-ORGAVOLT project and the Euroregion Aquitaine-Euskadi program. M.B. acknowledges support from the Departamento de Educacion of the Basque Government through a PhD grant, as well as from Euskampus and the DIPC at the initial stages of this work. R.E. and P.K. acknowledge financial support from the Fellows Gipuzkoa program of the Gipuzkoako Foru Aldundia through the FEDER funding scheme of the European Union, "Una manera de hacer Europa". ; Peer Reviewed

This paper was published in OPTICS LETTERS and is made available as an electronic reprint with the permission of OSA. The paper can be found at the following URL on the OSA website: http://dx.doi.org/10.1364/OL.39.001394. Systematic or multiple reproduction or distribution to multiple locations via electronic or other means is prohibited and is subject to penalties under law ; Intuitively, light impinging on a spatially mirror-symmetric object will be scattered equally into mirror-symmetric directions. This intuition can fail at the nanoscale if the polarization of the incoming light is properly tailored, as long as mirror symmetry is broken in the axes perpendicular to both the incident wave vector and the remaining mirror-symmetric direction. The unidirectional excitation of plasmonic modes using circularly polarized light has been recently demonstrated. Here, we generalize this concept and show that linearly polarized photons impinging on a single spatially symmetric scatterer created in a silicon waveguide are guided into a certain direction of the waveguide depending exclusively on their polarization angle and the structure asymmetry. Our work broadens the scope of polarization-induced directionality beyond plasmonics, with applications in polarization (de)multiplexing, unidirectional coupling, directional switching, radiation polarization control, and polarization-encoded quantum information processing in photonic integrated circuits ; This work has received financial support from the Spanish government (contracts Consolider EMET CSD2008-00066 and TEC2011-28664-C02-02) and GV (grant ACOMP/2013/013). F. J. R.-F. acknowledges support from grant FPI of GV. D. Puerto acknowledges support from grant Juan de la Cierva (JCI-2010-07479). ; Rodríguez Fortuño, FJ.; Puerto Garcia, D.; Griol Barres, A.; Bellieres, LC.; Martí Sendra, J.; Martínez Abietar, AJ. (2014). Sorting linearly polarized photons with a single scatterer. Optics Letters. 39(6):1394-1397. https://doi.org/10.1364/OL.39.001394 ; S ; 1394 ; 1397 ; 39 ...

The unprecedented advance experienced by nano- fabrication techniques and plasmonics research over the past few years has made possible the realization of nanophotonic systems entering into the so-called strong coupling regime between localized surface plasmon (LSP) modes and quantum emitters. Unfortunately, from a theoretical point of view, the field is hindered by the lack of analytical descriptions of the electro- magnetic interaction between strongly hybridized LSP modes and nanoemitters even within the Markovian approximation. This gap is tackled here by exploiting a conformal transformation where a bow-tie nanoantenna excited by a dipole is mapped into a periodic slab−dipole framework whose analytical solution is available. Solving the problem in the transformed space not only provides a straightforward analytical explanation for the original problem (validated using full-wave simulations) but also grants a deep physical insight and simple design guidelines to maximize the coupling between localized dipoles and the bow-tie LSP modes. The results presented here therefore pave the way for a full analytical description of realistic scenarios where quantum dots or dye molecules (modeled beyond a two-level system) are placed near a metallic bow-tie nanoantenna. ; This work was supported in part by the Spanish Government under contract TEC2014-51902-C2-2-R. V.P.-P. is sponsored by Spanish Ministerio de Educación, Cultura y Deporte under grant FPU AP-2012-3796. M.B. is sponsored by the Spanish Government via RYC-2011-08221. A.I.F.-D. acknowledges funding from EU Seventh Framework Programme under grant agreement FP7-PEOPLE-2013-CIG63099. Y.L. would like to acknowledge the funding support from Singapore Ministry of Education (MOE) under grant no. MOE2015-T2-1-145, and NTU-A*STAR Silicon Technologies Centre of Excellence under the program grant no. 11235150003. M.N.-C. was supported by an Imperial College Junior Research Fellowship and is now supported by a Birmingham Fellowship.

This is the peer reviewed version of the following article: M. Navarro-Cía, V. Pacheco-Peña, S. A. Kuznetsov, M. Beruete: Extraordinary THz Transmission with a Small Beam Spot: The Leaky Wave Mechanism. Advanced Optical Materials 2018, 1701312, which has been published in final form at https://doi.org/10.1002/adom.201701312. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. ; The discovery of extraordinary optical transmission (EOT) through patterned metallic foils in the late 1990s was decisive for the development of plasmonics and cleared the path to employ small apertures for a variety of interesting applications all along the electromagnetic spectrum. However, a typical drawback often found in practical EOT structures is the large size needed to obtain high transmittance peaks. Consequently, practical EOT arrays are usually illuminated using an expanded (mimicking a plane wave) beam. Here, it is shown with numerical and experimental results in the THz range that high transmittance peaks can be obtained even with a reduced illumination spot exciting a small number of holes, provided that the structure has a sufficient number of lateral holes out of the illumination spot. These results shed more light on the prominent role of leaky waves in the underlying physics of EOT and have a direct impact on potential applications. ; This work was partially supported by the Spanish Ministerio de Economía y Competitividad with European Union Fondo Europeo de Desarrollo Regional (FEDER) funds [TEC2014-51902-C2-2-R]. M.N.-C. acknowledges support from University of Birmingham [Birmingham Fellowship]. V.P.-P. was sponsored by Spanish Ministerio de Educación, Cultura y Deporte [formación de profesorado universitario (FPU) AP-2012-3796]. S.A.K. acknowledges support from the Novosibirsk State University (NSU) program 5-100 established by the Russian Ministry of Education and Science.

1452 1455 40 7 ; S ; "This paper was published in Optics Letters and is made available as an electronic reprint with the permission of OSA. The paper can be found at the following URL on the OSA website: http://dx.doi.org/10.1364/OL.40.001452. Systematic or multiple reproduction or distribution to multiple locations via electronic or other means is prohibited and is subject to penalties under law" [EN] Vanadium dioxide (VO2) is a metal-insulator transition (MIT) oxide recently used in plasmonics, metamaterials, and reconfigurable photonics. Because of the MIT, VO2 shows great change in its refractive index allowing for ultra-compact devices with low power consumption. We theoretically demonstrate a transverse electric (TE) and a transverse magnetic (TM) pass polarizer with an ultra-compact length of only 1 μm and tunable using the MIT of the VO2. During the insulating phase, both devices exhibit insertion losses below 2 dB at 1550 nm. Changing to the metallic phase, the unwanted polarization is attenuated above 15 dB while insertion losses are kept below 3 dB. Broadband operation over a range of 60 nm is also achieved. This work was supported by the European Commission under project FP7-ICT-2013-11-619456 SITOGA. Financial support from TEC2012-38540 LEOMIS is also acknowledged. L. Sanchez also acknowledges the Generalitat Valenciana for funding his grant in the context of the VALi+d program. Sánchez Diana, LD.; Lechago Buendía, S.; Sanchis Kilders, P. (2015). Ultra-compact TE and TM pass polarizers based on vanadium dioxide on silicon. Optics Letters. 40(7):1452-1455. https://doi.org/10.1364/OL.40.001452 Soref, R., & Larenzo, J. (1986). All-silicon active and passive guided-wave components for λ = 1.3 and 1.6 µm. IEEE Journal of Quantum Electronics, 22(6), 873-879. doi:10.1109/jqe.1986.1073057 Jalali, B., & Fathpour, S. (2006). Silicon Photonics. Journal of Lightwave Technology, 24(12), 4600-4615. doi:10.1109/jlt.2006.885782 Manolatou, C., Johnson, S. G., Fan, S., Villeneuve, P. R., Haus, H. A., & ...

The authors acknowledge support from an ETH Research Grant ETH-15 17-1 (R. S.), from an ETH Postdoctoral Fellowship FEL-21 15-2 and SNSF PRIMA Grant 179834 (E. S.), from a Postdoctoral fellowships programme "Beatriu de Pinós", funded by the Secretary of Universities and Research (Government of Catalonia) and by the Horizon 2020 programme of research and innovation of the European Union under the Marie Sklodwoska-Curie grant agreement no. 801370 (Grant 2018 BP 00029) (M. A. F. R.) and from a Gordon and Betty Moore Foundation Investigator Award on Aquatic Microbial Symbiosis (grant GBMF9197) (R. S.). The authors thank Dr. Heiko Wolf at IBM Research Zurich for insightful discussions. ; Colloidal patterning enables the placement of a wide range of materials into prescribed spatial arrangements, as required in a variety of applications, including micro- and nano-electronics, sensing, and plasmonics. Directed colloidal assembly methods, which exploit external forces to place particles with high yield and great accuracy, are particularly powerful. However, currently available techniques require specialized equipment, which limits their applicability. Here, we present a microfluidic platform to produce versatile colloidal patterns within a microchannel, based on sequential capillarity-assisted particle assembly (sCAPA). This new microfluidic technology exploits the capillary forces resulting from the controlled motion of an evaporating droplet inside a microfluidic channel to deposit individual particles in an array of traps microfabricated onto a substrate. Sequential depositions allow the generation of a desired spatial layout of colloidal particles of single or multiple types, dictated solely by the geometry of the traps and the filling sequence. We show that the platform can be used to create a variety of patterns and that the microfluidic channel easily allows surface functionalization of trapped particles. By enabling colloidal patterning to be carried out in a controlled environment, exploiting equipment routinely used in microfluidics, we demonstrate an easy-to-build platform that can be implemented in microfluidics labs. ; ETH Research Grant ETH-15 17-1 ; ETH Postdoctoral Fellowship FEL-21 15-2 ; SNSF PRIMA Grant 179834 ; Postdoctoral fellowships programme "Beatriu de Pinos" - Government of Catalonia ; Horizon 2020 programme of research and innovation of the European Union under the Marie Sklodwoska-Curie grant 801370 2018 BP 00029 ; Gordon and Betty Moore Foundation Investigator Award on Aquatic Microbial Symbiosis GBMF9197

Technologically useful and robust graphene-based interfaces for devices require the introduction of highly selective, stable, and covalently bonded functionalities on the graphene surface, whilst essentially retaining the electronic properties of the pristine layer. This work demonstrates that highly controlled, ultrahigh vacuum covalent chemical functionalization of graphene sheets with a thiol-terminated molecule provides a robust and tunable platform for the development of hybrid nanostructures in different environments. We employ this facile strategy to covalently couple two representative systems of broad interest: metal nanoparticles, via S–metal bonds, and thiol-modified DNA aptamers, via disulfide bridges. Both systems, which have been characterized by a multitechnique approach, remain firmly anchored to the graphene surface even after several washing cycles. Atomic force microscopy images demonstrate that the conjugated aptamer retains the functionality required to recognize a target protein. This methodology opens a new route to the integration of high-quality graphene layers into diverse technological platforms, including plasmonics, optoelectronics, or biosensing. With respect to the latter, the viability of a thiol-functionalized chemical vapor deposition graphene-based solution-gated field-effect transistor array was assessed. ; This work was supported by the European Union's Horizon 2020 research and innovation programme under grant agreement No 696656 (Graphene Flagship-core 1) and no 785219 (Graphene Flagship −core 2); UE FP7 ideas: ERC (grant ERC-2013-SYG-610256 Nanocosmos) and Spanish MINECO grants MAT2014-54231-C4-1-P, MAT2014-54231-C4-4-P, MAT2017-85089-C2-1-R, MAT2014-59772-C2-2-P, and BIO2016-79618-R (funded by EU under the FEDER programme), as well as the Nanoavansens program from the Community of Madrid (S2013/MIT-3029). This work has made use of the Spanish ICTS Network MICRONANOFABS partially supported by MINECO and also the ICTS NANBIOSIS, more specifically the Micro-Nano Technology Unit of the CIBER in Bioengineering, Biomaterials & Nanomedicine (CIBER-BBN) at the IMB-CNM. We are grateful to Matthias Muntwiler for his assistance with experiments in the PEARL beamline in the SLS facility. Finally, we acknowledge the TEM and ICP services at the CNB and ICMM institutes, respectively. CSS acknowledges the MINECO for a Juan de la Cierva Incorporación grant (IJCI-2014-19291). M. Marciello is grateful to the Comunidad de Madrid (CM) and European Social Fund (ESF) for supporting her research work through the I+D Collaborative Programme in Biomedicine NIETO-CM (B2017-BMD3731). ; Peer reviewed

Nanoscale charge control is a key enabling technology in plasmonics, electronic band structure engineering, and the topology of two-dimensional materials. By exploiting the large electron affinity of α-RuCl3, we are able to visualize and quantify massive charge transfer at graphene/α-RuCl3 interfaces through generation of charge-transfer plasmon polaritons (CPPs). We performed nanoimaging experiments on graphene/α-RuCl3 at both ambient and cryogenic temperatures and discovered robust plasmonic features in otherwise ungated and undoped structures. The CPP wavelength evaluated through several distinct imaging modalities offers a high-fidelity measure of the Fermi energy of the graphene layer: EF = 0.6 eV (n = 2.7 × 1013 cm–2). Our first-principles calculations link the plasmonic response to the work function difference between graphene and α-RuCl3 giving rise to CPPs. Our results provide a novel general strategy for generating nanometer-scale plasmonic interfaces without resorting to external contacts or chemical doping. ; Research at Columbia was supported as part of the Energy Frontier Research Center on Programmable Quantum Materials funded by the U.S. Department of Energy (DOE), Office of Science, Basic Energy Sciences (BES), under Award No. DE-SC0019443. J.Z., L.X., and A.R. were supported by the European Research Council (ERC-2015-AdG694097), the Cluster of Excellence "Advanced Imaging of Matter" (AIM) EXC 2056 - 390715994, funding by the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) under RTG 2247, Grupos Consolidados (IT1249-19) and SFB925 "Light induced dynamics and control of correlated quantum systems". J.Z. acknowledges funding received from the European Union Horizon 2020 research and innovation program under Marie Sklodowska-Curie Grant Agreement 886291 (PeSD-NeSL). J.Z., L.X., and A.R. would like to acknowledge Nicolas Tancogne-Dejean for fruitful discussions and also acknowledge support by the Max Planck Institute-New York City Center for Non-Equilibrium Quantum Phenomena. The Flatiron Institute is a division of the Simons Foundation. D.G.M. acknowledges support from the Gordon and Betty Moore Foundation's EPiQS Initiative, Grant GBMF9069. Work at ORNL was supported by the U.S. Department of Energy, Office of Science, Basic Energy Sciences, Materials Sciences and Engineering Division. K.W. and T.T. acknowledge support from the Elemental Strategy Initiative conducted by the MEXT, Japan, Grant JPMXP0112101001, JSPS KAKENHI Grant JP20H00354, and the CREST (JPMJCR15F3), JST. S.E.N. was supported by the Division of Scientific User Facilities of the U.S. DOE Basic Energy Sciences. M.M.F. acknowledges support from the Office of Naval Research Grant N00014-18-1-2722. D.N.B. is the Vannevar Bush Faculty ONR-VB: N00014-19-1-2630 and Moore investigator in Quantum Materials EPIQS program #9455. A.S.M acknowledges support from award 80NSSC19K1210 under the NASA Laboratory Analysis of Returned Samples program. ; Peer reviewed

In celebration of the 2015 International Year of Light, we highlight major breakthroughs in photonics for energy conversion and conservation. The section on energy conversion discusses the role of light in solar light harvesting for electrical and thermal power generation; chemical energy conversion and fuel generation; as well as photonic sensors for energy applications. The section on energy conservation focuses on solid-state lighting, flat-panel displays, and optical communications and interconnects ; A.F.N. acknowledges support from the Fundação de Amparo a Pesquisa no Estado de São Paulo (FAPESP) and the Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) of Brazil. D.O'C. acknowledges support from the U.S. National Science Foundation (Grant DMR- 1309459). J.J.P. acknowledges support from the U.S. Office of Naval Research. I.D.W.S. acknowledges support from the Engineering and Physical Sciences Research Council of the UK (Grants EP/K00042X and EP/L012294) and the European Research Council of the European Union (Grant 321305). N.T. acknowledges support from the U.S. National Science Foundation (Grants ECCS 1408051 and DMR 1505122)