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A groundbreaking text and professional resource on natural attenuation technologyNatural attenuation is rapidly becoming a widely used approach to manage groundwater and soil contamination by hazardous substances in petroleum-product releases and leachate from hazardous waste sites and landfills

Abstract. In this study, we assess the relationships between North Atlantic scale atmospheric regimes and extremes of precipitation and minimum temperature in the Iberian peninsula for an extended (DJFM) winter season. As found in previous studies, large scale atmospheric regimes are well represented in climate simulations while the extreme atmospheric variability is not. The relationship between some of these atmospheric regimes and the probability of occurrence of extreme values in simulations of present day climatic variability is validated here with daily observations at 68 meteorological stations all over the Iberian peninsula. Therefore, the possible changes in the probability of occurrence of winter extremes of minimum temperature and precipitation are obtained by projecting the changes in the probability of occurrence of the winter atmospheric regimes. The trends in the frequency of the observed large scale patterns give an indication of what can be expected in the next decades. For the long term (in a century), the changes are obtained directly from the comparison of the frequencies of the atmospheric regimes in the scenario simulations with those of the historical period. The projections obtained in this way are tested for consistency with the results obtained by comparing the changes in the extremes threshold values in the scenario with those of the historical simulations. The results point to a future with less precipitation extreme events and less minimum temperature extreme events in winter in the westerly central part of the Iberian peninsula.

AbstractThis study explores the relationship between railroad integration and regional development on the European periphery between 1870 and 1910, based on a regional data set including 291 spatial units. Railroad integration is proxied by railroad density, while per capita GDP is used as an indicator of economic development. The period under study is of particular relevance as it has been associated with the second wave of railroad construction in Europe and also coincides with the industrialization of most of the continent. Overall, we found that railroads had a significant and positive impact on the growth of per capita GDP across Europe. The magnitude of this relationship appears to be relatively modest, but the results obtained are robust with respect to a number of different specifications. From a geographical perspective, we found that railroads had a significantly greater influence on regions located in countries on the northern periphery of Europe than in other outlying areas. They also helped the economies of these areas to begin the process of catching up with the continent's industrialized core. In contrast, the regions on the southern periphery showed lower levels of economic growth, with this exacerbating the preexisting divergence in economic development. The expansion of the railroad network in them was unable to homogenize the diffusion of economic development and tended to further benefit the regions that were already industrialized. In most of the cases, the capital effect was magnified, and this contributed to the consolidation of newly created nation-states.

AbstractThere is a debate about whether coastal shipping experienced substantial productivity growth prior to the advent of steam power. To study changes over the long eighteenth century, this article uses thousands of coastal journey times culled from Board of Trade crew lists between 1835 and 1844 and coastal port books for the mid‐to‐late 1600s, along with a newly digitized coastal network. Comparisons between matched samples show that journey speeds, defined as miles sailed per day, were significantly higher in the crew lists compared to the port books, and that voyage cycle times, defined as days between starting two identical voyages, were substantially lower. The study also shows that voyage times in the east coast coal trade were substantially lower around 1840 than around 1700, but the difference was much smaller when peace years are compared. These new data imply that total factor productivity growth in the east coast coal trade was significant, especially if one accounts for gains from peace after 1815. The findings contribute to the larger literature studying the rate and sources of productivity growth during the industrial revolution.

A hybrid bilayer lipid membrane (hBLM), constructed with a 1-hexadecanethiol self-assembled interior leaflet and a 1,2-dipalmitoyl-sn-glycero-3-cytidine nucleolipid exterior leaflet, was deposited at the surface of a gold (111) electrode. This system was used to investigate the molecular recognition reaction between the cytosine moieties of the lipid head group with guanine molecules in the bulk electrolyte solution. Electrochemical measurements and photon polarization modulation infrared reflection absorption spectroscopy (PMIRRAS) were employed to characterize the system and determine the extent of the molecular recognition reaction. The capacitance of the hBLM-covered gold electrode was very low (~1 μF cm−2), therefore the charge density at the gold surface was small. Changing the electrode potential had a minimal effect on the complexation between the cytosine moieties and guanine molecules due to small changes in the static electric field across the membrane. This behavior favored the formation of the guanine–cytosine complex. ; Spanish Ministry of Economy and Competitiveness, Andalusian government, Discovery grant from Natural Sciences and Engineering Council of Canada.