In: Ecotoxicology and environmental safety: EES ; official journal of the International Society of Ecotoxicology and Environmental safety, Band 241, S. 113826
The interactions between electric and magnetic subsystems in a ferroelectric-ferromagnetic composite occur through mechanical forces. Here we discuss results of a systematic investigation on the strength of the magnetic response of the composite to an applied electric field, known as the converse magnetoelectric (CME) effect, and its dependence on the ferroic order parameters and volume fraction for the two phases. Studies were carried out on composites of lead zirconate titanate and 2-30-mu m-thick nickel zinc ferrite (NZFO) films grown by liquid phase epitaxy on lattice matched (100) and (111) MgO substrates. Ferromagnetic resonance was utilized to determine the strength of CME from data on electric field E induced shift in the resonance frequency and its dependence on ferrite film orientation and thickness as well as MgO substrate thickness. The CME coupling coefficient A was found to be a factor of 2 to 4 higher in samples with NZFO films with (100) orientation than for (111) films. A decrease in A was measured with increasing ferrite film thickness and a very significant enhancement in the strength of CME was measured for decreasing MgO thickness. A model for CME that takes into consideration the influence of nonferroic MgO substrate was developed, and estimated A values are in very good agreement with the data. The results presented here are also of importance for a new class of electric field tunable ferrite microwave devices. ; Public domain authored by a U.S. government employee
In: Ecotoxicology and environmental safety: EES ; official journal of the International Society of Ecotoxicology and Environmental safety, Band 289, S. 117644
MAX phases are gaining attention as precursors of two-dimensional MXenes that are intensively pursued in applications for electrochemical energy storage. Here, we report the preparation of V2SnC MAX phase by the molten salt method. V2SnC is investigated as a lithium storage anode, showing a high gravimetric capacity of 490 mAh g(-1) and volumetric capacity of 570 mAh cm(-3) as well as superior rate performance of 95 mAh g(-1) (110 mAh cm(-3)) at 50 C, surpassing the ever-reported performance of MAX phase anodes. Supported by operando X-ray diffraction and density functional theory, a charge storage mechanism with dual redox reaction is proposed with a Sn-Li (de)alloying reaction that occurs at the edge sites of V2SnC particles where Sn atoms are exposed to the electrolyte followed by a redox reaction that occurs at V2C layers with Li. This study offers promise of using MAX phases with M-site and A-site elements that are redox active as high-rate lithium storage materials. ; Funding Agencies|National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [51902215, 91426304, 21671195, 21805295, 51902320, 51902319, 21875271, U2004212]; China Postdoctoral Science FoundationChina Postdoctoral Science Foundation [2020M680082]; International Partnership Program of Chinese Academy of Sciences [174433KYSB20190019]; Leading Innovative and Entrepreneur Team Introduction Program of Zhejiang [2019R01003]; Ningbo top-talent team program; Swedish Government Strategic Research Area in Materials Science on Functional Materials at Linkoping University (Faculty Grant SFO Mat LiU) [200900971]; Knut and Alice Wallenberg FoundationKnut & Alice Wallenberg Foundation [KAW 2015.0043, 2020.0196]; Swedish Foundation for Strategic Research (SSF)Swedish Foundation for Strategic Research [EM16-0004, RIF 14-0074]
Abstract Background In order to compare the gene expression profiles of human embryonic stem cell (hESC) lines and their differentiated progeny and to monitor feeder contaminations, we have examined gene expression in seven hESC lines and human fibroblast feeder cells using Illumina ® bead arrays that contain probes for 24,131 transcript probes. Results A total of 48 different samples (including duplicates) grown in multiple laboratories under different conditions were analyzed and pairwise comparisons were performed in all groups. Hierarchical clustering showed that blinded duplicates were correctly identified as the closest related samples. hESC lines clustered together irrespective of the laboratory in which they were maintained. hESCs could be readily distinguished from embryoid bodies (EB) differentiated from them and the karyotypically abnormal hESC line BG01V. The embryonal carcinoma (EC) line NTera2 is a useful model for evaluating characteristics of hESCs. Expression of subsets of individual genes was validated by comparing with published databases, MPSS (Massively Parallel Signature Sequencing) libraries, and parallel analysis by microarray and RT-PCR. Conclusion we show that Illumina's bead array platform is a reliable, reproducible and robust method for developing base global profiles of cells and identifying similarities and differences in large number of samples.